N-(4-Bromophenyl)-N-phenylnaphthalen-1-amine

Base Information

• Chemical Name: N-(4-Bromophenyl)-N-phenylnaphthalen-1-amine
• CAS No.: 138310-84-6
• Molecular Formula: C22H16BrN
• Molecular Weight: 374.28
• Hs Code.: 2921499090
• European Community (EC) Number: 806-935-8
• DSSTox Substance ID: DTXSID30593374
• Nikkaji Number: J3.090.336F
• Wikidata: Q72511132
• Mol file: 138310-84-6.mol

Synonyms:138310-84-6;N-(4-Bromophenyl)-N-phenylnaphthalen-1-amine;N-(4-BROMOPHENYL)-N-PHENYL-1-NAPHTHALENAMINE;N-(4-bromophenyl)-N-phenyl-1-naphthylamine;1-Naphthalenamine, N-(4-bromophenyl)-N-phenyl-;N-(1-Naphthyl)-N-phenyl-4-bromoaniline;1-[N-(4-Bromophenyl)anilino]naphthalene;SCHEMBL1032732;DTXSID30593374;ABMCIJZTMPDEGW-UHFFFAOYSA-N;BCP14294;MFCD11046471;AKOS015911923;4-[(1-Naphthyl)phenylamino]bromobenzene;N-(4-bromophenyl)-1-naphthylphenylamine;p-Bromo-N-(1-naphthyl)-N-phenylaniline;AC-24436;AS-66963;(4-bromophenyl)naphthalen-1-yl-phenylamine;4-Bromo-4'-(1-naphthylphenylamino)benzene;DB-063246;B4299;F18764;A847350

Chemical Property of N-(4-Bromophenyl)-N-phenylnaphthalen-1-amine

Chemical Property:

• Vapor Pressure: 3.06E-10mmHg at 25°C
• Melting Point: 91.0 to 100.0 °C
• Refractive Index: 1.708
• Boiling Point: 502.9 °C at 760 mmHg
• PKA: -1.21±0.50(Predicted)
• Flash Point: 257.9 °C
• PSA: 3.24000
• Density: 1.381 g/cm³
• LogP: 7.07210
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 7.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 373.04661
• Heavy Atom Count: 24
• Complexity: 383

Purity/Quality:

99% ^*data from raw suppliers

N-(4-Bromophenyl)-N-phenylnaphthalen-1-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N(C2=CC=C(C=C2)Br)C3=CC=CC4=CC=CC=C43

Technology Process of N-(4-Bromophenyl)-N-phenylnaphthalen-1-amine

There total 8 articles about N-(4-Bromophenyl)-N-phenylnaphthalen-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,4-bromoiodobenzene (589-87-7) + N-phenyl-1-naphthylamine (90-30-2) → N-(4-bromophenyl)-N-phenyl-1-naphthylamine (138310-84-6)

Guidance literature:

With palladium diacetate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; sodium t-butanolate; In toluene; at 100 ℃; for 12h; chemoselective reaction; Inert atmosphere;

DOI:10.1016/j.tet.2015.01.028

Reference yield: 70.0%

→ N-(4-bromophenyl)-N-phenyl-1-naphthylamine (138310-84-6)

Guidance literature:

With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide; In 5,5-dimethyl-1,3-cyclohexadiene; for 18h; Reflux;

Reference yield: 65.0%

1.4-dibromobenzene (106-37-6) + N-phenyl-1-naphthylamine (90-30-2) → N-(4-bromophenyl)-N-phenyl-1-naphthylamine (138310-84-6)

Guidance literature:

With 1,1'-bis(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate; In toluene; at 90 ℃; for 15h; Inert atmosphere;

DOI:10.1016/j.tet.2009.04.024

upstream raw materials:

1,4-bromoiodobenzene

N-phenyl-1-naphthylamine

copper

sodium t-butanolate

Downstream raw materials:

{4-[(naphthalen-1-yl)(phenyl)amino]phenyl}boronic acid

N-(1-naphthyl)-N-phenyl-p-(2'-thiophenyl)aniline

1-(N-naphthalen-1-yl-N-phenylamino)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene

N-phenyl-N-(4-(5-(6-(1-phenyl-1H-benzo[d]imidazol-2-yl)pyridin-3-yl)pyrazin-2-yl)phenyl)naphthalen-1-amine

Refernces

• 1、 Zheng, Zhiwen,Dong, Qingchen,Gou, Liao,Su, Jian-Hua,Huang, Jinhai. "Novel hole transport materials based on N,N′-disubstituted-dihydrophenazine derivatives for electroluminescent diodes". . p. 9858 - 9865. Retrieved 2014.
• 2、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF". Paragraph 0187; 0192-0194. . Retrieved 2019/12/31.
• 3、 -. "Compound Containing Ring Linked Via Carbazole and Fluorene And Organic Electronic Element Using The Same, Terminal Thereof". Paragraph 0247; 0248-0251. . Retrieved 2017/10/21.