DIPHENYLPHOSPHINOBENZENE-3-SULFONIC ACID SODIUM SALT

Base Information

• Chemical Name: DIPHENYLPHOSPHINOBENZENE-3-SULFONIC ACID SODIUM SALT
• CAS No.: 63995-75-5
• Molecular Formula: C18H15 O3 P S . Na
• Molecular Weight: 364.337
• Hs Code.: 2904100000
• Mol file: 63995-75-5.mol

Synonyms:Benzenesulfonicacid, 3-(diphenylphosphino)-, sodium salt (9CI); (m-Sulfonatophenyl)diphenylphosphinesodium salt; (m-Sulfophenyl)diphenylphosphine sodium salt;3-(Diphenylphosphino)benzenesulfonic acid sodium salt;Diphenyl(3-sulfophenyl)phosphine sodium salt;Diphenylphosphinobenzene-m-sulfonic acid sodium salt; Monosodiummono(m-sulfonatophenyl)diphenylphosphine; Sodium(diphenylphosphino)benzene-3-sulfonate; Sodiumdiphenyl(3-sulfonatophenyl)phosphine dihydrate; TPPMS; [3-(Sodiumsulfonato)phenyl]diphenylphosphine

Chemical Property of DIPHENYLPHOSPHINOBENZENE-3-SULFONIC ACID SODIUM SALT

Chemical Property:

• Melting Point: 236 - 239°C
• PSA: 79.17000
• LogP: 3.42970
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility.: DMSO (Sparingly), Water (Slightly)

Purity/Quality:

98%,99%, ^*data from raw suppliers

Sodium Diphenylphosphinobenzene-3-sulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 2816567
• Hazard Codes: C
• Statements: 34
• Safety Statements: 22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Sodium Diphenylphosphinobenzene-3-sulfonate is a water-soluble phosphine ligand used in the formation of water-soluble catalysts. 3-(Diphenylphosphino)benzenesulfonic Acid Sodium Salt can be used as anti-cancer gold compounds.

Technology Process of DIPHENYLPHOSPHINOBENZENE-3-SULFONIC ACID SODIUM SALT

There total 4 articles about DIPHENYLPHOSPHINOBENZENE-3-SULFONIC ACID SODIUM SALT which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium 3-(diphenylphosphinyl)benzenesulfonate (112998-09-1) → sodium 3-(diphenylphosphanyl)benzenesulfonate (63995-75-5)

Guidance literature:

With trichlorosilane; triphenylphosphine; In toluene; at 110 ℃; Inert atmosphere;

DOI:10.1021/jo801418a

Reference yield: 60.0%

triphenylphosphine (603-35-0) → sodium 3-(diphenylphosphanyl)benzenesulfonate (63995-75-5) + disodium P-phenyl-3,3'-phosphinediyl-bis(benzenesulfonate)

Guidance literature:

triphenylphosphine; With sulfuric acid; In sulfuric acid; at 0 - 20 ℃; for 21h;

In sodium hydroxide; at 0 ℃;

DOI:10.1016/S0040-4039(00)00651-1

Reference yield: 59.0%

triphenylphosphine (603-35-0) → C18H13O7PS2(2-)*2Na(1+) + sodium 3-(diphenylphosphanyl)benzenesulfonate (63995-75-5) + sodium 3-(diphenylphosphinyl)benzenesulfonate (112998-09-1) + disodium P-phenyl-3,3'-phosphinediyl-bis(benzenesulfonate)

Guidance literature:

triphenylphosphine; With oleum; at 0 - 20 ℃; for 20h;

With sodium hydroxide; In water; at 0 ℃;

DOI:10.1002/ejic.200901002

upstream raw materials:

triphenylphosphine

sodium 3-(diphenylphosphinyl)benzenesulfonate

Downstream raw materials:

(1,2-dicarboxyethenyl)diphenyl(3-sulfophenyl)phosphonium inner salt, sodium salt

(1,2-dicarboxyethenyl)diphenyl(3-sulfophenyl)phosphonium inner salt, sodium salt

(1,2-dicarboxyethenyl)diphenyl(3-sulfophenyl)phosphonium inner salt, sodium salt

(1,2-dicarboxyethenyl)diphenyl(3-sulfophenyl)phosphonium inner salt, sodium salt

Refernces

• 1、 Huo, Congde,Wang, Cheng,Hu, Dongcheng,Jia, Xiaodong. "A clean and efficient conversion of aldehydes into the corresponding nitriles using ionic supported triphenylphosphine and CBr4". . p. 442 - 444. Retrieved 2013/08/23.
• 2、 -. "ZWITTERIONIC PHOSPHONIUM SALTS". Page/Page column 27-28. . Retrieved 2010/04/03.