Dichlorotetrakis(triphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: Dichlorotetrakis(triphenylphosphine)ruthenium(II)
• CAS No.: 15555-77-8
• Molecular Formula: C₇₂H₆₀Cl₂P₄Ru
• Molecular Weight: 1221.14
• European Community (EC) Number: 624-278-3
• DSSTox Substance ID: DTXSID10475129
• Mol file: 15555-77-8.mol

Synonyms:15555-77-8;Dichlorotetrakis(triphenylphosphine)ruthenium(II);dichlororuthenium;triphenylphosphane;Ruthenium, dichlorotetrakis(triphenylphosphine)-;Dichlororuthenium;Triphenylphosphane;RuCl2(PPh3)4;Ruthenium,dichlorotetrakis(triphenylphosphine)-;DTXSID10475129;AKOS025117509;Dichlororuthenium--triphenylphosphane (1/4);F16278;A936812;Dichlorotetrakis(triphenylphosphine)ruthenium( cento)

Chemical Property of Dichlorotetrakis(triphenylphosphine)ruthenium(II)

Chemical Property:

• Vapor Pressure: 4.74E-05mmHg at 25°C
• Melting Point: 159 °C
• Boiling Point: 360°C at 760 mmHg
• Flash Point: 181.7°C
• PSA: 54.36000
• LogP: 15.15820
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 1220.206596
• Heavy Atom Count: 79
• Complexity: 204

Purity/Quality:

99% ^*data from raw suppliers

Dichlorotetrakis(triphenylphosphine)ruthenium(II) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36/37-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru]Cl
• Uses: Catalyst for:Selective hydrogenation of maleic anhydride or succinic anhydrideSythesis of portions of the natural antibiotic tetrodecamycinOxidation of hydroxamic acidHydroesterification reactionsHydroboration of alkenesOxidation of sulfide

Technology Process of Dichlorotetrakis(triphenylphosphine)ruthenium(II)

There total 2 articles about Dichlorotetrakis(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ruthenium(III) chloride trihydrate + triphenylphosphine (603-35-0) → dichlorotetrakis(triphenylphosphine)ruthenium(II) (15555-77-8,86470-43-1)

Guidance literature:

In methanol; for 8h; Reflux; Inert atmosphere;

DOI:10.14233/ajchem.2019.22162

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) + triphenylphosphine (603-35-0) → dichlorotetrakis(triphenylphosphine)ruthenium(II) (15555-77-8,86470-43-1)

Guidance literature:

In methanol; vigorous shaking and filtering, allowing soln. to stand under N2 atmosphere for 24 h, washing precipitate with methanol and ether, drying in vacuum at 60°C;;

DOI:10.1016/0022-1902(66)80191-4

Reference yield: 100.0%

dichlorotetrakis(triphenylphosphine)ruthenium(II) (15555-77-8,86470-43-1) + 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (161265-03-8) → RuCl2(PPh3)(Xantphos) (1579977-69-7)

Guidance literature:

In ⁽²⁾H₈-toluene; for 3h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/om4011998

upstream raw materials:

ruthenium(III) chloride trihydrate

triphenylphosphine

Downstream raw materials:

[RuCl(C₆H₃(CH₂NMe₂)2-2,6-N,C,N')(PPh₃)]

RuCl(P(C₆H₅)3)(C₆H₂(C₆H₅)(CH₂N(CH₃)2)2)

RuCl(P(C₆H₅)3)(C₆H₂(Si(CH₃)3)(CH₂N(CH₃)2)2)

cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

Refernces