Diiodo(p-cymene)ruthenium(II) dimer

Base Information

• Chemical Name: Diiodo(p-cymene)ruthenium(II) dimer
• CAS No.: 90614-07-6
• Molecular Formula: C₂₀H₂₈I₄Ru₂
• Molecular Weight: 978.2
• Hs Code.: 28439000
• Mol file: 90614-07-6.mol

Synonyms:Di-mu-iodobis(p-cymene)iodoruthenium(II)

Chemical Property of Diiodo(p-cymene)ruthenium(II) dimer

Chemical Property:

• Appearance/Colour: brown/yellow solid
• Melting Point: 234-236 °C
• PSA: 0.00000
• LogP: 9.05200
• Storage Temp.: Refrigerator (+4°C)
• Sensitive.: Moisture & Light Sensitive
• Water Solubility.: insoluble

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diiodo-di-Iodobis(p-cymene)diruthenium(II)Dimer,Ru21.4% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 68-52/53-36-22
• Safety Statements: 61-36/37-26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Diiodo(p-cymene)ruthenium(II) dimer can be applied as a catalyst for many reactions such as ruthenium-catalyzed hydrogenation, preparation of Walphos-type ferrocenyl-aryl diphosphine ligands, ruthenium-catalyzed synthesis reactions, and enantioselective hydrogenation of ketones and olefins.

Technology Process of Diiodo(p-cymene)ruthenium(II) dimer

There total 1 articles about Diiodo(p-cymene)ruthenium(II) dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

[(p-Me-C6H4-CH(CH3)2)2Ru2Cl2(μ-Cl)(μ-H)] (281676-60-6,90720-60-8) + hydrogen iodide (10034-85-2) → [(p-Me-C6H4-CH(CH3)2)2Ru2I2(μ-I)2] (873313-23-6,281676-68-4,90614-07-6)

Guidance literature:

In tetrahydrofuran; water; byproducts: HCl, H2; (N2); addn. of concd. aq. soln. of HI (4 equiv.) to soln. of Ru complex(1 equiv.) in THF; reflux for 5 h; filtration, evapn., washing with H2O, tacking up in CH2Cl2, drying withMgSO4, filtration, evapn.;

DOI:10.1016/S0022-328X(00)00155-8

upstream raw materials:

[(p-Me-C6H4-CH(CH3)2)2Ru2Cl2(μ-Cl)(μ-H)]

hydrogen iodide

Refernces