1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

Base Information

• Chemical Name: 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
• CAS No.: 29964-62-3
• Molecular Formula: C28H28Cl2P2Pd
• Molecular Weight: 603.804
• Hs Code.: 28439000
• European Community (EC) Number: 678-067-6
• DSSTox Substance ID: DTXSID30450296
• Mol file: 29964-62-3.mol

Synonyms:29964-62-3;1,4-Bis(diphenylphosphino)butane-palladium(II) chloride;1,4-Butylenebis(diphenylphosphine)palladium dichloride;[1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride;dichloropalladium;4-diphenylphosphanylbutyl(diphenyl)phosphane;Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II);Pd(dppb)Cl2;SCHEMBL146934;DTXSID30450296;JQXJBXVWVPVTOO-UHFFFAOYSA-L;AKOS024258506;LS-0009;SC10418;BP-12221;FT-0650167;F10007;1,4-Butylenebis(diphenylphosphine)palladiumdichloride;J-503968;1,4-bis(diphenylphosphino)butane palladium(II)chloride;1,4-bis(diphenylphosphino)butane palladium (II) chloride;[1,4-bis(diphenylphosphino)butane]palladium(ii)dichloride;[1.4-bis(diphenylphosphino)butane] palladium (II) chloride;1,4-bis(diphenylphosphino)-butane palladium (II) chloride;1,4-bis(diphenylphosphino)butane palladium(II) dichloride;1,4-bis-(diphenylphosphino)-butane palladium (II) chloride;1.4-bis-(diphenylphosphino)-butane palladium (II) chloride;(Butane-1,4-diyl)bis(diphenylphosphane)--dichloropalladium (1/1);1,4-Bis(diphenylphosphino)butane-palladium(II) chloride, >=95.0%;Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex, PdCl2(dppb)

Chemical Property of 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

Chemical Property:

• Appearance/Colour: yellow solid
• Vapor Pressure: 2.92E-11mmHg at 25°C
• Melting Point: 285-305 °C
• Boiling Point: 542°C at 760 mmHg
• Flash Point: 299.5°C
• PSA: 27.18000
• LogP: 7.41140
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: Soluble in ethanol, benzene, and ethereal solvents.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 602.00781
• Heavy Atom Count: 33
• Complexity: 364

Purity/Quality:

99% ^*data from raw suppliers

[1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride >96.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 36/37/38
• Safety Statements: 24/25-36-27

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(CCCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Pd]Cl
• Uses: Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.

Technology Process of 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

There total 9 articles about 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.9%

hydrogenchloride (7647-01-0,15364-23-5) + palladium (7440-05-3) + 1,4-di(diphenylphosphino)-butane (7688-25-7) → [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride (29964-62-3)

Guidance literature:

hydrogenchloride; palladium; With nitric acid; In water;

1,4-di(diphenylphosphino)-butane; In water; N,N-dimethyl-formamide; at 50 ℃; for 1h;

Reference yield: 97.0%

dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4) + 1,4-di(diphenylphosphino)-butane (7688-25-7) → [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride (29964-62-3)

Guidance literature:

In benzene; at 110 ℃; for 48h; Schlenk technique; Inert atmosphere;

DOI:10.1021/jacs.5b08476

Reference yield: 97.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + 1,4-di(diphenylphosphino)-butane (7688-25-7) → PdCl2(PPh2(CH2)4PPh2) (29964-62-3)

Guidance literature:

In chloroform; for 1h;

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

1,4-di(diphenylphosphino)-butane

dichloro bis(acetonitrile) palladium(II)

dichloro(cycloocta-1,5-diene)palladium (II)

Downstream raw materials:

Pd(1,2-bis(diphenylphosphino)butane)(OSO₂CF₃)2

cis-diethyl-1,4-bis(diphenylphosphino)butane-palladium

Pd(C₆H₅)2PC₄H₈P(C₆H₅)2(CF₃SO₃)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((C₆H₅)2PC₄H₈P(C₆H₅)2)(CF₃SO₃)2

Refernces

• 1、 Pagot, Matteo,Toniolo, Luigi,Antonetti, Claudia,Forte, Claudia,Galletti, Anna Maria Raspolli. "Carbon monoxide-ethene copolymerization catalyzed by [PdCl2(dppb)] in H2O-H(CH2)nCOOH (dppb = 1,4-bis(diphenyphosphino)butane; N = 0, 1, 2)". . p. 202 - 208. Retrieved 2015.
• 2、 Alves, Kamilla M.,Ayalla, Alejando P.,Batista, Alzir A.,Dutra, Jocely De L.,Ellena, Javier,Gon?alves, Pablo J.,Guedes, Adriana P. M.,Honorato, Jo?o,Li?o, Luciano M.,Velozo-Sa, Vivianne S.. "Meso -Tetra-(4-pyridyl)porphyrin/palladium(ii) complexes as anticancer agents". . p. 16254 - 16264. Retrieved 2021/11/27.
• 3、 Bagum, Halima,Christensen, Kirsten E.,Genov, Miroslav,Pretsch, Alexander,Pretsch, Dagmar,Moloney, Mark G.. "Synthetic Access to 3-Substituted Pyroglutamic Acids from Tetramate Derivatives of Serine, Threonine, allo-Threonine, and Cysteine". . p. 10257 - 10279. Retrieved 2019/08/20.