Triphenyl(propyl)phosphonium

Base Information

• Chemical Name: Triphenyl(propyl)phosphonium
• CAS No.: 15912-75-1
• Molecular Formula: C21H22P
• Molecular Weight: 305.379
• Hs Code.: 29319090
• European Community (EC) Number: 240-056-5,228-330-2
• DSSTox Substance ID: DTXSID40936051
• Nikkaji Number: J215.852C
• Wikidata: Q72514829
• ChEMBL ID: CHEMBL3558360
• Mol file: 15912-75-1.mol

Synonyms:triphenyl(propyl)phosphonium;15912-75-1;triphenyl(propyl)phosphanium;Triphenylpropylphosphonium bromide;Triphenylpropylphosphonium;Propyltriphenylphosphonium;SCHEMBL2229284;CHEMBL3558360;MSXNDXIAUQJHNS-UHFFFAOYSA-;DTXSID40936051;triphenyl-propylphosphanium bromide;BCP24508;EINECS 240-056-5;STL059012;AKOS005711535;CS-W009936;D77701

Chemical Property of Triphenyl(propyl)phosphonium

Chemical Property:

• Appearance/Colour: white to light yellow solid
• Melting Point: 235-238°C(lit.)
• Boiling Point: 176-180oC
• Flash Point: 137 °F
• PSA: 13.59000
• Density: 0.904
• LogP: 1.39450
• Water Solubility.: soluble
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 305.145912699
• Heavy Atom Count: 22
• Complexity: 260

Purity/Quality:

99% ^*data from raw suppliers

n-Propyltriphenylphosphoniumbromide 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R21/22:; R36/37/38:
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Triphenyl(propyl)phosphonium

There total 1 articles about Triphenyl(propyl)phosphonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ N-propyl-triphenyl-phosphonium cation (15912-75-1)

Guidance literature:

(C6H5)3P, 1-Brompropan;

DOI:10.1021/jo00981a013

Reference yield:

Iron(III) nitrate nonahydrate + manganese(II) chloride tetrahydrate + N-propyl-triphenyl-phosphonium cation (15912-75-1) + oxalic acid (144-62-7,97993-78-7) → C3H7P(C6H5)3(1+)*Mn(2+)*Fe(3+)*3C2O4(2-)=C3H7P(C6H5)3MnFe(C2O4)3

Guidance literature:

With HCl; In not given; the soln. of cation in the form of the Cl or Br salt in methanol or water was mixed with a soln. of Fe(NO3)3*9H2O in water, solid MnCl2*4H2O wasadded, then 6 drops of 1 M HCl was added, 0.6 M soln. of oxalic acid wa s added; ppt. was washed with water and methanol, dried in vac. over blue silica gel; elem. anal.;

DOI:10.1039/b107057f

Reference yield:

Iron(III) nitrate nonahydrate + ferrous(II) sulfate heptahydrate + N-propyl-triphenyl-phosphonium cation (15912-75-1) + oxalic acid (144-62-7,97993-78-7) → C3H7P(C6H5)3(1+)*Fe(2+)*Fe(3+)*3C2O4(2-)=C3H7P(C6H5)3Fe2(C2O4)3

Guidance literature:

With HCl; In not given; the soln. of cation in the form of the Cl or Br salt in methanol or water was mixed with a soln. of Fe(NO3)3*9H2O in water, solid FeSO4 was added, then 6 drops of 1 M HCl was added, 0.6 M soln. of oxalic acid was added; ppt. was washed with water and methanol, dried in vac. over blue silica gel; elem. anal.;

DOI:10.1039/b107057f