Iron(III) dimethyldithiocarbamate

Base Information

• Chemical Name: Iron(III) dimethyldithiocarbamate
• CAS No.: 14484-64-1
• Deprecated CAS: 1135443-06-9,13494-27-4,301-05-3,64070-92-4
• Molecular Formula: C9H18FeN3S6
• Molecular Weight: 416.505
• Hs Code.: 29302000
• European Community (EC) Number: 238-484-2
• UN Number: 3077,2771
• ICSC Number: 0792
• Wikipedia: Iron_tris(dimethyldithiocarbamate)
• Mol file: 14484-64-1.mol

Synonyms:ferbam;Ferbam 76;ferric dimethyldithiocarbamate;iron N,N-dimethyldithiocarbamate

Chemical Property of Iron(III) dimethyldithiocarbamate

Chemical Property:

• Appearance/Colour: odourless black solid
• Vapor Pressure: 2 x 10-11 Pa (est.)
• Melting Point: 180 °C (dec.)
• Boiling Point: 129.4 °C at 760 mmHg
• Flash Point: 32 °C
• PSA: 181.89000
• Density: 0.21[at 20℃]
• LogP: 3.08870
• Storage Temp.: 0-6°C
• Water Solubility.: 130 mg l-1 (room temperature)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 415.917435
• Heavy Atom Count: 19
• Complexity: 228
• Transport DOT Label: Class 9

Purity/Quality:

99.9% ^*data from raw suppliers

Ferbam ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi; N
• Hazard Codes: Xi,N
• Statements: 36/37/38-50/53
• Safety Statements: 26-36/37/39-61-60

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CN(C)C(=S)[S-].CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Fe+3]
• Inhalation Risk: Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
• Effects of Short Term Exposure: The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the central nervous system.
• Effects of Long Term Exposure: Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the nervous system and thyroid.
• Uses: Nonphytotoxic fungicide used to control scab on fruits and other crops. Ferbam is a protective fungicide applied to foliage to control scab on pome fruit, peach leaf curl, blue mould on tobacco and other diseases on many other crops. It is often used in combinations with other dithiocarbamates to extend the spectrum of activity. Fruit fungicide.

Technology Process of Iron(III) dimethyldithiocarbamate

There total 10 articles about Iron(III) dimethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Ammonium iron sulfate + N,N-dimethyldithiocarbamic acid (79-45-8) → tris(N,N-dimethyldithiocarbamato)iron(III) (14484-64-1,21696-59-3)

Guidance literature:

Ammonium iron sulfate; N,N-dimethyldithiocarbamic acid; In ethanol; water; N,N-dimethyl-formamide; at 20 ℃; for 0.166667h;

With ammonium hydroxide; In ethanol; water; N,N-dimethyl-formamide; at 130 ℃; for 72h; pH=5; Temperature;

Reference yield: 60.0%

diiron nonacarbonyl (15321-51-4) + tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten → tris(N,N-dimethyldithiocarbamato)iron(III) (14484-64-1,21696-59-3) + Fe(η2-S2CNMe2)2 (52690-05-8,15339-38-5) + Fe(CO)2(η2-S2CNMe2)2 (36309-89-4,93221-07-9)

Guidance literature:

In toluene; Irradiation (UV/VIS); irradiation with visible light for 2 h under argon;; solvent removed in vacuo, chromd. (silica gel, elution with petroleum ether/CH2Cl2 1/1 gave (CO)2-complex, elution with CH2Cl2 gave Fe(dtc)2);

DOI:10.1016/S0020-1693(00)86021-1

Reference yield: 59.0%

cis-[Fe2(NCMe)2(η5-cyclopentadienyl)2(μ-CS)(μ-CSMe)]OSO2CF3 + sodium N,N-dimethyldithiocarbamate dihydrate (128-04-1) → tris(N,N-dimethyldithiocarbamato)iron(III) (14484-64-1,21696-59-3) + [Fe2(μ-CS)(μ-CSMe)(μ-S2CNMe2)(η5-cyclopentadienyl)2]

Guidance literature:

In acetone; standard inert atmosphere techniques; soln. of ligand (1.15 equiv.) in acetone added to soln. of Fe complex in acetone; stirred at room temp. for 30 min; residue chromd. (alumina column, CH2Cl2-petroleum ether); first brown band collected, crystd. from CH2Cl2-hexane at -20°C (thiocarbyne Fecomplex); second purple band collected, Fe(S2CNMe2)3 crystd.; elem. ana l.;

DOI:10.1016/S0022-328X(02)01652-2

upstream raw materials:

sodium dimethyldithiocarbamate

iron(III)

iron(II)

Thiram

Refernces

• 1、 -. "Preparation method and application of iron dithiocarbamate complex catalyst". Paragraph 0018-0019; 0020-0021; 0022-0023. . Retrieved 2020/09/16.
• 2、 Mathur, Pradeep,Thimmappa. "Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species". . p. 119 - 122. Retrieved 2008/10/08.