Ethylenediamine monohydrochloride

Base Information

• Chemical Name: Ethylenediamine monohydrochloride
• CAS No.: 333-18-6
• Molecular Formula: C2H8N2^.2(HCl)
• Molecular Weight: 133.021
• Hs Code.: 29212100
• European Community (EC) Number: 242-181-0
• NSC Number: 263495,163962
• UNII: 67M1ZLR9SC
• DSSTox Substance ID: DTXSID10885022
• Wikidata: Q27264147
• ChEMBL ID: CHEMBL4085198
• Mol file: 333-18-6.mol

Synonyms:1,2-diaminoethane;1,2-ethanediamine;edamine;ethane-1,2-diamine;ethyl diamine;ethylenediamine;ethylenediamine (1:1) sulfate;ethylenediamine (1:1) sulfite;ethylenediamine conjugate acid;ethylenediamine dihydrobromide;ethylenediamine dihydrochloride;ethylenediamine dihydrogen iodide;ethylenediamine dihydroiodide;ethylenediamine dinitrate;ethylenediamine hydrochloride;ethylenediamine monohydrochloride;ethylenediamine phosphate;ethylenediamine sulfate;ethylenediamine, 3H-labeled cpd

Chemical Property of Ethylenediamine monohydrochloride

Chemical Property:

• Appearance/Colour: white crystalline powder
• Melting Point: >300 °C(lit.)
• Boiling Point: 119.7 °C at 760 mmHg
• Flash Point: 33.9 °C
• PSA: 52.04000
• Density: 1.159g/cm3
• LogP: 1.90840
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Solubility.: water: soluble100mg/mL, clear, colorless to very faintly yellow
• Water Solubility.: 300 g/L (20 ºC)
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 96.0454260
• Heavy Atom Count: 5
• Complexity: 6

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ethylenediamine dihydrochloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-36/37/38-42/43
• Safety Statements: 22-26-36/37-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(CN)N.Cl
• Uses: Ethylenediamine dihydrochloride is used as stabilizer in steroid creams and rubber latex; inhibitor in antifreeze solutions and cooling fluids; in floor-polish remover; in nystatin cream and aminophylline; epoxy-curing agent; accelerator in color development baths in photography; in veterinary preparations; in electroplating and electrophoretic gels, dyes, fungicides, insecticides, synthetic waxes, textile lubricants, and eye and nose drops; solvent for casein, albumin, shellac. Ethylenediamine dihydrochloride was used in modified ethylenediamine condensation method for fluorimetric determination of catecholamines. It was used to investigate the luminescence properties of complexes of EuIII and TbIII with ethylenediamine. It was used in the synthesis of 1,3,5-tris(4,5-dihydro-1H-imidazol-2-yl)benzene3 Ethylenediamine dihydrochloride was used in modified ethylenediamine condensation method for fluorimetric determination of catecholamines. It was used to investigate the luminescence properties of complexes of EuIII and TbIII with ethylenediamine. It was used in the synthesis of 1,3,5-tris(4,5-dihydro-1H-imidazol-2-yl)benzene.

Technology Process of Ethylenediamine monohydrochloride

There total 21 articles about Ethylenediamine monohydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N,N'-ethylenediphthalimide (607-26-1) → 1,2-diaminoethane dihydrochloride (333-18-6)

Guidance literature:

N,N'-ethylenediphthalimide; With potassium hydroxide; In water; at 20 ℃;

With hydrogenchloride; In water; pH=< 2;

DOI:10.1021/ja5101036

Reference yield: 94.0%

imidazolidone (120-93-4) → 1,2-diaminoethane dihydrochloride (333-18-6)

Guidance literature:

With hydrogenchloride; at 100 ℃; for 0.0333333h; microwave irradiation;

DOI:10.1080/00397910701464951

Reference yield: 85.0%

ethylenediamine (107-15-3,85404-18-8) + acryloyl chloride (814-68-6,25189-84-8) → N,N'-ethylenebisacrylamide (2956-58-3) + 1,2-diaminoethane dihydrochloride (333-18-6)

Guidance literature:

In acetonitrile; for 2h; Ambient temperature;

upstream raw materials:

ethylenediamine

acryloyl chloride

chlorine

acetic acid

Downstream raw materials:

2-undecyl-2-imidazoline

1,1'-(ethane-1,2-diyl)diguanidine

ethylene diurea

[(2-{[(cyano)(phenyl)methyl]amino}ethyl)amino](phenyl)acetonitrile

Refernces

• 1、 Chouaib, Hassen,Kamoun, Slaheddine,Karoui, Sahel. "Synthesis, X-ray powder diffraction study, thermal analysis, Hirshfeld surface analysis and optical properties of new crystalline polymer: {(C2H10N2)(MnCl(NCS)2)2}n". . . Retrieved 2020/08/10.
• 2、 Kiely, Donald E.,Vishwanathan, Arvind,Jarman, Bevan P.,Manley-Harris, Merilyn. "Synthesis of poly(galactaramides) from alkylene- and substituted alkylenediammonium galactarates". experimental part. p. 348 - 368. Retrieved 2010/01/16.