Triethyltin bromide

Base Information

• Chemical Name: Triethyltin bromide
• CAS No.: 2767-54-6
• Molecular Formula: C6H15 Br Sn
• Molecular Weight: 285.799
• Hs Code.: 29310099
• European Community (EC) Number: 220-443-5
• UN Number: 3265
• UNII: UOP17166KC
• DSSTox Substance ID: DTXSID9040712
• Wikidata: Q27291173
• Mol file: 2767-54-6.mol

Synonyms:bromotriethylstannane;triethyltin bromide

Chemical Property of Triethyltin bromide

Chemical Property:

• Appearance/Colour: colorless liq.
• Vapor Pressure: 0.147mmHg at 25°C
• Melting Point: -13.5 °C
• Refractive Index: n20/D 1.526(lit.)
• Boiling Point: 223 °C at 760 mmHg
• Flash Point: 99.4 °C
• PSA: 0.00000
• Density: 1.63 g/mL at 25 °C(lit.)
• LogP: 3.38650
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 285.93792
• Heavy Atom Count: 8
• Complexity: 51.3
• Transport DOT Label: Corrosive

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethyltin Bromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+N
• Hazard Codes: T+,N
• Statements: 26/27/28-50/53
• Safety Statements: 26-27-28-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[Sn](CC)(CC)Br

Technology Process of Triethyltin bromide

There total 110 articles about Triethyltin bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tetraethyltin (597-64-8) → triethyltin bromide (2767-54-6)

Guidance literature:

With bromine; In tetrachloromethane; a soln. of Br2 in CCl4 was added dropwise to the pure SnEt4 at 0°C; purification by vac. fractionation; UV;

DOI:10.1016/0584-8539(84)80199-3

Reference yield: 70.0%

tetraethyltin (597-64-8) + isopropyl bromide (75-26-3) → triethyltin bromide (2767-54-6)

Guidance literature:

aluminium trichloride; In benzene;

Reference yield:

chlorotriethylstannane (994-31-0) + benzyl bromide (100-39-0) → triethyltin bromide (2767-54-6) + benzyl chloride (100-44-7)

Guidance literature:

With N-benzyl pyridinium halide; at 50 ℃; Equilibrium constant;

DOI:10.1016/S0022-328X(00)81789-1

upstream raw materials:

triethyltin iodide

benzyl bromide

chlorotriethylstannane

Bromotrichloromethane

Downstream raw materials:

2-triethylstannyloxazole

triethylvinylstannane

p-methoxyphenyl-triethyltin

(C₂H₅)3SnOOCH₂C₆H₅

Refernces

• 1、 Mirskov,Rakhlin,Adamovich,Voronkov. "Plasmochemical synthesis of thin layers of the sulfur doped silicon dioxide". . p. 184 - 185. Retrieved 2009.
• 2、 Shostakovskii,M.F. et al.. "". . . Retrieved 1964.
• 3、 Rakhlin,Podgorbunskaya,Voronkov. "Homolytic reactions of N-bromohexamethyldisilazane with trialkyl(phenylalkoxy) derivatives of silicon and tin". . p. 930 - 935. Retrieved 2011/01/09.