CID 53384608

Base Information

• Chemical Name: CID 53384608
• CAS No.: 15522-71-1
• Molecular Formula: C33H57EuO6
• Molecular Weight: 701.772
• Hs Code.: 2914509090
• European Community (EC) Number: 239-565-5
• Mol file: 15522-71-1.mol

Synonyms:15522-71-1;T1265;Europium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)

Chemical Property of CID 53384608

Chemical Property:

• Vapor Pressure: 0.00138mmHg at 25°C
• Melting Point: 187-191 °C
• Boiling Point: 275°C
• Flash Point: 109.7°C
• PSA: 102.42000
• LogP: 7.82070
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 9
• Exact Mass: 702.33675
• Heavy Atom Count: 40
• Complexity: 199

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)(C)C(=CC(=O)C(C)(C)C)[O-].CC(C)(C)C(=CC(=O)C(C)(C)C)[O-].CC(C)(C)C(=CC(=O)C(C)(C)C)[O-].[Eu+3]
• Isomeric SMILES: CC(/C(=C\C(=O)C(C)(C)C)/[O-])(C)C.CC(/C(=C\C(=O)C(C)(C)C)/[O-])(C)C.CC(/C(=C\C(=O)C(C)(C)C)/[O-])(C)C.[Eu+3]
• Uses: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) (CAS# 15522-71-1) is a lanthanide-containing coordination complex which is used as an NMR shift reagent. Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) has also been used as a doping agent in GaN light-emitting diodes, providing improved luminescence properties.

Technology Process of CID 53384608

There total 2 articles about CID 53384608 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[tris(dipivaloylmethanato)diaqua]Eu(III) (499204-17-0) → tris(dipivaloylmethanato)europium(III) (15522-71-1)

Guidance literature:

In neat (no solvent); sublimation at 180-200°C (10E-2 Torr);

DOI:10.1021/jp711305u

Reference yield:

2,2,6,6-tetramethylheptane-3,5-dione (1118-71-4) + europium(III) nitrate hexahydrate → tris(dipivaloylmethanato)europium(III) (15522-71-1)

Guidance literature:

In ethanol; crystg. 3X from dry n-hexane; vac. drying in presence of P2O5;

DOI:10.1007/BF01914213

Reference yield:

tris(dipivaloylmethanato)europium(III) (15522-71-1) + Triphenylphosphine oxide (791-28-6) → Eu(C11H19O2)3*C18H15PO

Guidance literature:

In Petroleum ether; refluxing, stirring, cooling;

upstream raw materials:

2,2,6,6-tetramethylheptane-3,5-dione

[tris(dipivaloylmethanato)diaqua]Eu(III)

Refernces

• 1、 Eliseeva, Svetlana V.,Kotova, Oxana V.,Gumy, Frederic,Semenov, Sergey N.,Kessler, Vadim G.,Lepnev, Leonid S.,Buenzli, Jean-Claude G.,Kuzmina, Natalia P.. "Role of the ancillary ligand N,N-dimethylaminoethanol in the sensitization of EuIII and TbIII luminescence in dimeric β-diketonates". . p. 3614 - 3626. Retrieved 2008.