methyl 3-methoxyoct-2-enoate

Base Information

• Chemical Name: methyl 3-methoxyoct-2-enoate
• CAS No.: 116429-06-2
• Molecular Formula: C₁₀H₁₈O₃
• Molecular Weight: 186.251
• Mol file: 116429-06-2.mol

Synonyms:methyl 3-methoxyoct-2-enoate

Chemical Property of methyl 3-methoxyoct-2-enoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 3-methoxyoct-2-enoate

There total 2 articles about methyl 3-methoxyoct-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl (E)-oct-2-enoate (7367-81-9) → methyl 3-oxooctanoate (22348-95-4) + methyl 3-methoxy-2-octenoate (116429-06-2)

Guidance literature:

With methanol; water; oxygen; palladium dichloride; In N,N-dimethyl acetamide; at 80 ℃; for 3h; under 4560.31 Torr; regioselective reaction; Autoclave;

DOI:10.1002/anie.201301611

Reference yield:

methanol (67-56-1) + methyl 2-octynoate (111-12-6,53073-28-2) → methyl 3-oxooctanoate (22348-95-4) + methyl 3-methoxyoct-2-enoate (116429-06-2) + Methyl 3,3-dimethoxy-octanoate (83578-30-7)

Guidance literature:

With mercury(II) diacetate; toluene-4-sulfonic acid; at 53 ℃; for 72h; Product distribution; reaction with various quantities of Hg(OAc)2, absence and presence 0.1percent TsOH, at various time;

upstream raw materials:

methanol

methyl 2-octynoate

methyl (E)-oct-2-enoate

Refernces

• 1、 Bassetti, Mauro,Floris, Barbara. "Metalation of Alkynes. Part 2. Behaviour of Alkynes with Mercury(II)Acetate in Methanol: a Systematic Reinvestigation". . p. 227 - 234. Retrieved 2007/10/02.