tetraphosphorus decasulfide

Base Information

• Chemical Name: tetraphosphorus decasulfide
• CAS No.: 15857-57-5
• Molecular Formula: P₄S₁₀
• Molecular Weight: 444.555
• Mol file: 15857-57-5.mol

Synonyms:tetraphosphorus decasulfide

Chemical Property of tetraphosphorus decasulfide

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphosphorus decasulfide

There total 16 articles about tetraphosphorus decasulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosphorus sulfide (12037-82-0) + triphenylstibine sulfide → tetraphosphorus decasulfide (15857-57-5) + tetraphosphorus nonasulfide (25070-46-6) + β-P4S9 (28315-95-9)

Guidance literature:

In carbon disulfide; absence of air and moisture; molar ratio P4S7:Ph3SbS=4:1, room temp., 2 h; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;

DOI:10.1021/ic9614881

Reference yield:

phosphorus sulfide (1314-85-8) + triphenyl arsine sulfide (3937-40-4) → tetraphosphorus decasulfide (15857-57-5) + phosphorus sulfide (12037-82-0) + tetraphosphorus nonasulfide (25070-46-6) + β-P4S8 (169833-95-8)

Guidance literature:

In carbon disulfide; absence of air and moisture; molar ratio P4S3:Ph3AsS=1.2:1, stirring for2 h; product mixt. not sepd., detd by (31)P-NMR spectroscopy;

DOI:10.1021/ic9614881

Reference yield:

phosphorus sulfide (12037-82-0) + triphenyl arsine sulfide (3937-40-4) → tetraphosphorus decasulfide (15857-57-5) + tetraphosphorus nonasulfide (25070-46-6) + β-P4S8 (169833-95-8) + β-P4S9 (28315-95-9)

Guidance literature:

In carbon disulfide; absence of air and moisture; molar ratio P4S7:Ph3AsS=3:1, room temp., 2 h; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;

DOI:10.1021/ic9614881

upstream raw materials:

sulfur

hexamethyldisilathiane

Bis(trifluormethyl)-thiophosphinsaeurebromid

phosphorus

Downstream raw materials:

monothioorthophosphoric acid

trichlorothiophosphine

carbon oxide sulfide

O,O-diisopropyl hydrogen phosphorodithioate

Refernces

• 1、 Jason, Mark E.,Ngo, Toan,Rahman, Shahidur. "Products and Mechanisms in the Oxidation of Phosphorus by Sulfur at Low Temperature". . p. 2633 - 2640. Retrieved 2008/10/09.
• 2、 Andrews, Lester,Thompson, Craig,Démarcq, Michel C.. "Infrared spectra of P4S10, P4S9, and P4S7 in solid argon". . p. 3173 - 3175. Retrieved 2008/10/08.