(HC₆F₄C₆F₄)Au(C₄H₈S)

Base Information

• Chemical Name: (HC₆F₄C₆F₄)Au(C₄H₈S)
• CAS No.: 90635-26-0
• Molecular Formula: C₁₆H₉AuF₈S
• Molecular Weight: 582.267
• Mol file: 90635-26-0.mol

Synonyms:(HC₆F₄C₆F₄)Au(C₄H₈S)

Chemical Property of (HC₆F₄C₆F₄)Au(C₄H₈S)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (HC₆F₄C₆F₄)Au(C₄H₈S)

There total 1 articles about (HC₆F₄C₆F₄)Au(C₄H₈S) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

n-butyllithium (109-72-8,29786-93-4) + (tetrahydrothiophene)gold(I) chloride (39929-21-0) + 4,4'-dibromo-2,3,5,6,2',3',5',6'-octafluoro-1,1'-biphenyl (10386-84-2) → (HC6F4C6F4)Au(C4H8S) (90635-26-0) + [(μ-4,4'-C6F4C6F4)(Au(tetrahydrothiophene))2] (90635-27-1)

Guidance literature:

In diethyl ether; to 4,4'-BrC6F4-C6F4Br soln. at -78°C and under N2, LiC4H9 added dropwise, stirred for 45 min, Au complex added, stirred for 30 min at -78°C, warmed to room temp. for 3 h; filtered in air through anhyd. MgSO4, concd., pptd. (hexane), filtrate concd., ppt. filtered off, recrystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1016/0022-328X(84)85015-9

Reference yield: 87.0%

(HC6F4C6F4)Au(C4H8S) (90635-26-0) → (Ph3P)Au(octafluorobiphenyl) (90635-28-2)

Guidance literature:

With PPh₃; In not given; to complex soln. in ether or CH2Cl2 ligand added, stirred at room temp.for 30 min; concd., pptd. (hexane); elem. anal.;

DOI:10.1016/0022-328X(84)85015-9

Reference yield: 77.0%

(HC6F4C6F4)Au(C4H8S) (90635-26-0) + bis-diphenylphosphinomethane (2071-20-7) → [((HC6F4C6F4)Au)2(CH2(P(C6H5)2)2)] (90635-29-3)

Guidance literature:

In not given; to complex soln. in ether or CH2Cl2 ligand added, stirred at room temp.for 30 min; concd., pptd. (hexane); elem. anal.;

DOI:10.1016/0022-328X(84)85015-9

upstream raw materials:

n-butyllithium

(tetrahydrothiophene)gold(I) chloride

4,4'-dibromo-2,3,5,6,2',3',5',6'-octafluoro-1,1'-biphenyl

Downstream raw materials:

(Ph₃P)Au(octafluorobiphenyl)

[N(P(C₆H₅)3)2]⁽¹⁺⁾*[(HC₆F₄C₆F₄)AuCl]^(1-)=[N(P(C₆H₅)3)2][(HC₆F₄C₆F₄)AuCl]

[((HC₆F₄C₆F₄)Au)2(CH₂(P(C₆H₅)2)2)]

[Au(C₆H₄(As(CH₃)2)2)2]⁽¹⁺⁾*[Au(C₆F₄C₆F₄H)2]^(1-)=[Au(C₆H₄(As(CH₃)2)2)2][Au(C₆F₄C₆F₄H)2]

Refernces