diethyl 1-(p-chlorobenzoyloxy)octylphosphonate

Base Information

• Chemical Name: diethyl 1-(p-chlorobenzoyloxy)octylphosphonate
• CAS No.: 256511-59-8
• Molecular Formula: C₁₉H₃₀ClO₅P
• Molecular Weight: 404.871
• Mol file: 256511-59-8.mol

Synonyms:diethyl 1-(p-chlorobenzoyloxy)octylphosphonate

Chemical Property of diethyl 1-(p-chlorobenzoyloxy)octylphosphonate

Chemical Property:

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Technology Process of diethyl 1-(p-chlorobenzoyloxy)octylphosphonate

There total 1 articles about diethyl 1-(p-chlorobenzoyloxy)octylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

Octanal (124-13-0) + (4-chloro-benzoyl)-phosphonic acid diethyl ester (10570-46-4) → diethyl 1-(p-chlorobenzoyloxy)octylphosphonate (256511-59-8)

Guidance literature:

With samarium; diiodomethane; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at 20 ℃; for 3h;

DOI:10.1021/jo991357s

Reference yield: 98.0%

diethyl 1-(p-chlorobenzoyloxy)octylphosphonate (256511-59-8) → diethyl octylphosphonate (1068-07-1)

Guidance literature:

With samarium diiodide; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1021/jo991357s

Reference yield:

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + diethyl 1-(p-chlorobenzoyloxy)octylphosphonate (256511-59-8) → diethyl 1-(1'-hydroxycyclohexyl)octylphosphonate

Guidance literature:

With samarium diiodide; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1021/jo991357s

upstream raw materials:

Octanal

(4-chloro-benzoyl)-phosphonic acid diethyl ester

Downstream raw materials:

diethyl octylphosphonate

Refernces