Pentafluorpropionan stribrny

Base Information

• Chemical Name: Pentafluorpropionan stribrny
• CAS No.: 509-09-1
• Molecular Formula: C3H F5 O2 . Ag
• Molecular Weight: 270.892
• Hs Code.: 2915900090
• European Community (EC) Number: 208-093-1
• NSC Number: 133452
• Mol file: 509-09-1.mol

Synonyms:SILVER PENTAFLUOROPROPIONATE;509-09-1;Pentafluorpropionan stribrny;Propionic acid, silver salt;SCHEMBL621694;WLN: OVXFFXFFF &-AG-;Propionic acid, silver(1+) salt;NSC133452;N-(2-HYDROXYETHYL)ASPARTICACID;NSC-133452

Chemical Property of Pentafluorpropionan stribrny

Chemical Property:

• Melting Point: 242-244 °C(lit.)
• Boiling Point: 93.5°Cat760mmHg
• Flash Point: 10.3°C
• PSA: 26.30000
• Density: g/cm³
• LogP: 1.19150
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 1
• Exact Mass: 270.89476
• Heavy Atom Count: 11
• Complexity: 148

Purity/Quality:

98%min ^*data from raw suppliers

Silver pentafluoropropionate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,Xi
• Hazard Codes: Xn,Xi
• Statements: 22-37/38-41
• Safety Statements: 26-37/39

MSDS Files:

Useful:

• Canonical SMILES: C(=O)(C(C(F)(F)F)(F)F)O.[Ag]

Technology Process of Pentafluorpropionan stribrny

There total 1 articles about Pentafluorpropionan stribrny which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pentafluoropropionic acid (422-64-0) + silver carbonate → silver(I) pentafluoropropionate (509-09-1)

Guidance literature:

In acetonitrile; at 20 - 60 ℃; for 1.25h;

Reference yield: 98.7%

silver(I) pentafluoropropionate (509-09-1) + triphenylphosphine (603-35-0) → tris(triphenylphosphine)silver(I) pentafluoropropionate (667423-27-0)

Guidance literature:

In dichloromethane; under N2; soln. of PPh3 in CH2Cl2 slowly added to suspn. of C2F5CO2Ag inCH2Cl2 at 40°C (molar ratio = 3:1); after 2 h mixt. concd.; cold pentane (-70°C) added; ppt. recrystd. from THF/pentane; elem. anal.;

DOI:10.1016/S0020-1693(03)00468-7

Reference yield: 96.0%

1,1',2,2',3,3',4,4'-octamethylferrocene (59568-28-4) + silver(I) pentafluoropropionate (509-09-1) → ((CH3)4C5H)2Fe(1+)*C2F5CO2(1-)=[((CH3)4C5H)2Fe][C2F5CO2] (1384437-37-9)

Guidance literature:

In acetone; byproducts: Ag; aq. soln. of Ag compd. added to acetone soln. of Fe (1.1:1 molar ratio),mixt. stirred for 30 min; filtered, evapd., extd. (DCM), org. layer washed (H2O), dried (MgSO4), recrystd. (DCM/hexane), elem. anal.;

DOI:10.1016/j.jorganchem.2012.04.005

upstream raw materials:

pentafluoropropionic acid

Downstream raw materials:

C₁₈H₁₀F₁₀O₄Te

C₂₀H₁₄F₁₀O₆Te

(cyclohexylisocyanide)gold pentafluoropropionate

[Pd(O₂CCF₂CF₃-O)2(1,1'-bis(diphenylphosphino)ferrocene)]

Refernces