Niobium phosphide

Base Information

• Chemical Name: Niobium phosphide
• CAS No.: 12034-66-1
• Molecular Formula: NbP
• Molecular Weight: 123.88
• European Community (EC) Number: 234-810-2
• Wikipedia: Niobium_phosphide
• Wikidata: Q18212218
• Mol file: 12034-66-1.mol

Synonyms:Niobium phosphide;phosphanylidyneniobium;12034-66-1;EINECS 234-810-2;Q18212218

Chemical Property of Niobium phosphide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.86120
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 123.88014
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Phosphides
• Canonical SMILES: P#[Nb]

Technology Process of Niobium phosphide

There total 17 articles about Niobium phosphide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

gallium (7440-55-3) + niobium + phosphorus + barium (7440-39-3) → gallium phosphide (12063-98-8) + barium phosphide + niobium monophosphide (12034-66-1)

Guidance literature:

In neat (no solvent, solid phase); react. Ba:Ga:P (1:2:2) in sealed Nb tube;

DOI:10.1021/ic100940b

Reference yield:

niobium + phosphorus → niobium monophosphide (12034-66-1)

Guidance literature:

With iodine; In neat (no solvent); transport reaction, van-Arkel method; heating Nb, P and I2 in quartz ampoule in temp. drop from 1000-800°C for 20 days;; single crystals;;

DOI:10.1016/0022-5088(65)90078-0

Reference yield:

niobium + phosphorus → niobium monophosphide (12034-66-1)

Guidance literature:

at 800 ℃; for 48h;

DOI:10.1038/nmat4457

upstream raw materials:

sodium pyrophosphate

Refernces

• 1、 Xu,Greenblatt,Emge,H?hn,Hughbanks,Tian. "Crystal Structure, Electrical Transport, and Magnetic Properties of Niobium Monophosphide". . p. 845 - 849. Retrieved 1996.
• 2、 Wang,McDonald,Mar. "Ternary early-transition-metal palladium pnictides Zr3Pd4P3, Hf3Pd4P3, HfPdSb, and Nb5Pd4P4". . p. 4936 - 4941. Retrieved 2000.
• 3、 Ripley, R. L.. "". . p. 496 - 503. Retrieved 1962.
• 4、 Chen, Hongxiang,Yang, Dongliang,Zhang, Qinghua,Jin, Shifeng,Guo, Liwei,Deng, Jun,Li, Xiaodong,Chen, Xiaolong. "A Series of MAX Phases with MA-Triangular-Prism Bilayers and Elastic Properties". . p. 4576 - 4580. Retrieved 2019.
• 5、 He, Hua,Stearrett, Ryan,Nowak, Edmund R.,Bobev, Svilen. "BaGa2Pn2 (Pn = P, As): New semiconducting phosphides and arsenides with layered structures". . p. 7935 - 7940. Retrieved 2010.