Allyloxytrimethylsilane

Base Information

• Chemical Name: Allyloxytrimethylsilane
• CAS No.: 18146-00-4
• Molecular Formula: C6H14OSi
• Molecular Weight: 130.262
• Hs Code.: 29319090
• European Community (EC) Number: 242-031-4
• DSSTox Substance ID: DTXSID6066319
• Nikkaji Number: J207.940B
• Wikidata: Q72437380
• Mol file: 18146-00-4.mol

Synonyms:Allyloxytrimethylsilane;18146-00-4;trimethyl(prop-2-enoxy)silane;Silane, trimethyl(2-propenyloxy)-;Allyl trimethylsilyl ether;Silane, trimethyl(2-propen-1-yloxy)-;O-Trimethylsilylallyl alcohol;Trimethyl(2-propenyloxy)silane;Trimethylallyloxysilane;Allyloxytrimethylsilane, 98%;Allyl alcohol, TMS derivative;EINECS 242-031-4;MFCD00008643;(allyloxy)trimethylsilane;Trimethyl Allyloxysilane;allyloxy-trimethyl-silane;Me3SiO-CH2-CH=CH2;1-Trimethylsiloxy-2-propene;Silane, (allyloxy)trimethyl-;1-Trimethylsilyloxy-2-propene;SCHEMBL336085;DTXSID6066319;Allyl alcohol, trimethylsilyl ether;trimethyl(prop-2-en-1-yloxy)silane;AKOS015839130;AS-80569;A0927;FT-0622051;D88353;J-011584

Chemical Property of Allyloxytrimethylsilane

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 38mmHg at 25°C
• Melting Point: <0 °C
• Refractive Index: n20/D 1.397(lit.)
• Boiling Point: 103 °C at 760 mmHg
• Flash Point: -0.556 °C
• PSA: 9.23000
• Density: 0.791 g/cm³
• LogP: 2.02390
• Storage Temp.: 2-8°C
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 130.081391600
• Heavy Atom Count: 8
• Complexity: 73.1

Purity/Quality:

98% ^*data from raw suppliers

Allyloxytrimethylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, Xi
• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)OCC=C
• Uses: Allyloxytrimethylsilane is used in the synthesis of metalated dienes via an isomerization-elimination sequence. Allyloxytrimethylsilane [3-(Trimethylsiloxy)propene] was used in the synthesis of trimethylsilyl protected (3-hydroxypropyl)-trimethoxysilane. Used in preparation of electrical materials, OLED, and in Pharma industry.

Technology Process of Allyloxytrimethylsilane

There total 20 articles about Allyloxytrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

allyl alcohol (107-18-6) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → allyloxytrimethylsilane (18146-00-4)

Guidance literature:

With chloro-trimethyl-silane; at 20 ℃; for 6h;

DOI:10.1016/j.tetlet.2016.01.059

Reference yield: 99.0%

3-(trimethylsilyl)-2-oxazolidinone (43112-38-5) + allyl alcohol (107-18-6) → allyloxytrimethylsilane (18146-00-4)

Guidance literature:

chloro-trimethyl-silane; at 0 ℃; for 0.0166667h;

Reference yield: 95.2%

chloro-trimethyl-silane (75-77-4) + allyl alcohol (107-18-6) → allyloxytrimethylsilane (18146-00-4)

Guidance literature:

With triethylamine; at 20 ℃; for 0.05h; Inert atmosphere;

DOI:10.1002/jccs.201300586

upstream raw materials:

chloro-trimethyl-silane

allyl alcohol

1,1,1,3,3,3-hexamethyl-disilazane

dimethyldimethoxysilan

Downstream raw materials:

3-Trimethylsilyloxy-3-benzoyloxy-propen-⁽¹⁾

Trimethylmethoxysilane

Allyloxy-methoxy-dimethyl-silane

((E)-1-Allyl-2-methyl-penta-1,4-dienyl)-benzene

Refernces

• 1、 Seyferth,D. et al.. "-". . p. 4079 - 4081. Retrieved 1966.
• 2、 -. "A 2 - ((4R, 6S) - 6-substituted methyl-2-substituent -1,3-dioxane-4-yl) acetate preparation method". Paragraph 0070; 0071. . Retrieved 2017/02/24.
• 3、 Pakhomov, Alexey A.,Kononevich, Yuriy N.,Stukalova, Maria V.,Svidchenko, Evgeniya A.,Surin, Nikolay M.,Cherkaev, Georgy V.,Shchegolikhina, Olga I.,Martynov, Vladimir I.,Muzafarov, Aziz M.. "Synthesis and photophysical properties of a new BODIPY-based siloxane dye". supporting information. p. 979 - 982. Retrieved 2016/02/18.