Dichloroethylphenylsilane

Base Information

• Chemical Name: Dichloroethylphenylsilane
• CAS No.: 1125-27-5
• Molecular Formula: C₈H₁₀Cl₂Si
• Molecular Weight: 205.159
• European Community (EC) Number: 214-407-8
• UN Number: 2435
• UNII: Z8JOW05OJM
• DSSTox Substance ID: DTXSID80883656
• Nikkaji Number: J7.448I
• Wikidata: Q27295147
• Mol file: 1125-27-5.mol

Synonyms:Dichloroethylphenylsilane;ETHYLPHENYLDICHLOROSILANE;1125-27-5;dichloro-ethyl-phenylsilane;Phenylethyldichlorosilane;Ethyl phenyl dichlorosilane;Silane, dichloroethylphenyl-;Benzene, (dichloroethylsilyl)-;HSDB 443;EINECS 214-407-8;UNII-Z8JOW05OJM;UN2435;Z8JOW05OJM;BRN 2936355;4-16-00-01521 (Beilstein Handbook Reference);Dichloro(ethyl)(phenyl)silane;thylphnyldichlorosilane;Ethylphenyldichlorsilan;EPS (CHRIS Code);C8H10Cl2Si;dichloro(ethyl)phenylsilane;C8-H10-Cl2-Si;SCHEMBL115193;DTXSID80883656;MFCD00053199;NA2435;AKOS024462673;SILANE, ETHYL PHENYL DICHLORO-;LS-145170;FT-0694946;Ethylphenyldichlorosilane [UN2435] [Corrosive];Ethylphenyldichlorosilane [UN2435] [Corrosive];Q27295147

Chemical Property of Dichloroethylphenylsilane

Chemical Property:

• Vapor Pressure: 0.13mmHg at 25°C
• Refractive Index: 1.5321
• Boiling Point: 225.3°Cat760mmHg
• Flash Point: 85.5°C
• PSA: 0.00000
• Density: 1.12g/cm³
• LogP: 2.83330
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 203.9928822
• Heavy Atom Count: 11
• Complexity: 119
• Transport DOT Label: Corrosive

Purity/Quality:

98% ^*data from raw suppliers

ETHYLPHENYLDICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chlorosilanes
• Canonical SMILES: CC[Si](C1=CC=CC=C1)(Cl)Cl

Technology Process of Dichloroethylphenylsilane

There total 18 articles about Dichloroethylphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bromobenzene (108-86-1,52753-63-6) + ethyltrichlorosilane (115-21-9) → dichloro(ethyl)phenylsilane (1125-27-5,18447-29-5)

Guidance literature:

bromobenzene; With magnesium; In tetrahydrofuran;

ethyltrichlorosilane; In tetrahydrofuran; at 20 ℃;

DOI:10.1016/S0022-328X(01)00664-7

Reference yield: 29.0%

triethylsilyl chloride (994-30-9) + diphenylsilyl dichloride (80-10-4) → chloro(diethyl)(phenyl)silane (17876-59-4) + chloro(ethyl)(diphenyl)silane (18407-41-5) + dichloro(ethyl)phenylsilane (1125-27-5,18447-29-5)

Guidance literature:

With aluminum (III) chloride; at 120 ℃; for 3h; Overall yield = 60 %;

DOI:10.1134/S1070363215030111

Reference yield: 26.0%

diethyldichlorosilane (1719-53-5) + dichloromethylphenylsilane (149-74-6) → dichloro(ethyl)methylsilane (4525-44-4) + dichloro(ethyl)phenylsilane (1125-27-5,18447-29-5) + dimethylsilicon dichloride (75-78-5,30107-43-8) + diphenylsilyl dichloride (80-10-4)

Guidance literature:

With aluminum (III) chloride; at 120 ℃; for 3h; Concentration; Time;

DOI:10.1134/S1070363215030111

upstream raw materials:

ethyltrichlorosilane

ethene

dichlorophenylsilane

diethyl ether

Downstream raw materials:

dimethylethylphenylsilane

(5S,6S)-2-ethyl-5,6-dimethoxy-2-phenyl-1,3-dioxa-2-silacycloheptane

2-Ethyl-6-methyl-2-phenyl-[1,3,6,2]dioxazasilocane

2-ethyl-2,6-diphenyl-1,3-dioxa-6-aza-2-silacyclooctane

Refernces

• 1、 Li, Yanfei,Wang, Ying,Xiong, Tao,Zhang, Ge,Zhang, Qian. "Asymmetric Synthesis of Silicon-Stereogenic Silanes by Copper-Catalyzed Desymmetrizing Protoboration of Vinylsilanes". supporting information. p. 11927 - 11931. Retrieved 2020/05/22.
• 2、 Homsi, Fadi,Hosoi, Kazushi,Nozaki, Kyoko,Hiyama, Tamejiro. "Solid phase cross-coupling reaction of aryl(halo)silanes with 4-iodobenzoic acid". . p. 208 - 216. Retrieved 2007/10/03.