Tricyclopentylphosphine

Base Information

• Chemical Name: Tricyclopentylphosphine
• CAS No.: 7650-88-6
• Molecular Formula: C15H27P
• Molecular Weight: 238.35
• European Community (EC) Number: 423-150-2,624-629-0
• DSSTox Substance ID: DTXSID9074353
• Nikkaji Number: J1.149.496J
• Wikidata: Q72510543
• Mol file: 7650-88-6.mol

Synonyms:Tricyclopentylphosphine;7650-88-6;Tricyclopentylphosphane;Phosphine, tricyclopentyl-;MFCD00269834;Tricyclopentylphosphine, 97%;SCHEMBL190432;DTXSID9074353;DHWBYAACHDUFAT-UHFFFAOYSA-N;AKOS015840755;AS-58034;NS00007647;T2248;E79067

Chemical Property of Tricyclopentylphosphine

Chemical Property:

• Refractive Index: n20/D 1.538(lit.)
• Boiling Point: 332.7±9.0 °C(Predicted)
• Flash Point: 210oC
• PSA: 13.59000
• Density: 0.986 g/mL at 20oC(lit.)
• LogP: 5.29610
• Sensitive.: air sensitive
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 238.185037859
• Heavy Atom Count: 16
• Complexity: 169

Purity/Quality:

99.9% ^*data from raw suppliers

Tricyclopentylphosphine, min. 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 17-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CCC(C1)P(C2CCCC2)C3CCCC3

Technology Process of Tricyclopentylphosphine

There total 1 articles about Tricyclopentylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclopentylmagnesium chloride (32916-51-1) → tricyclopentylphosphine (7650-88-6)

Guidance literature:

cyclopentylmagnesium chloride; With phosphorus trichloride; In tetrahydrofuran; at 10 - 30 ℃; for 5h;

With sulfuric acid; In tetrahydrofuran; water; toluene;

Reference yield: 92.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + phenyldiazomethane (908094-04-2) + tricyclopentylphosphine (7650-88-6) → RuCl2(=CHPh)(PCp3)2

Guidance literature:

In dichloromethane; (Ar); stirring (-70 to -60°C, 5-10 min, room temp., 30 min); washing (methanol); elem. anal.;

DOI:10.1021/ja952676d

Reference yield: 79.0%

α,α,α-tris(azidomethyl)toluene (162463-15-2) + tricyclopentylphosphine (7650-88-6) → α,α,α-tris[((tricyclopentylphosphoranylidene)amino)methyl]toluene (866775-56-6)

Guidance literature:

In toluene; at 60 ℃;

DOI:10.1016/j.tet.2007.05.022

upstream raw materials:

cyclopentylmagnesium chloride

Downstream raw materials:

α,α,α-tris[((tricyclopentylphosphoranylidene)amino)methyl]toluene

bis(tricyclohexylphosphine)platinum⁽⁰⁾

Refernces