3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone

Base Information

• Chemical Name: 3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone
• CAS No.: 92631-83-9
• Molecular Formula: C₁₉H₂₀O₁₁
• Molecular Weight: 424.361
• Mol file: 92631-83-9.mol

Synonyms:3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone

Chemical Property of 3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone

There total 5 articles about 3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

UDP-glucose (133-89-1) + maclurin (519-34-6) → 3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone (92631-83-9)

Guidance literature:

With C-glycosyltransferase from Mangifera indica; In methanol; at 40 ℃; for 12h; pH=6.6; Enzymatic reaction;

DOI:10.1002/chem.201600411

Reference yield:

maclurin 3-C-(6''-O-p-hydroxybenzoyl)-β-D-glucoside (92665-82-2) → 3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone (92631-83-9) + 4-hydroxy-benzoic acid (99-96-7)

Guidance literature:

In water; at 35 ℃; hesperidinase;

Reference yield:

maclurin 3-C-(2''-O-p-hydroxybenzoyl-6''-O-galloyl)-β-D-glucoside (92631-85-1) → 3,4,5-trihydroxybenzoic acid (149-91-7) + 3-glucosyl-2,3′,4,4′,6-pentahydroxybenzophenone (92631-83-9) + 4-hydroxy-benzoic acid (99-96-7)

Guidance literature:

In water; at 37 ℃; hesperidinase;

upstream raw materials:

maclurin 3-C-(6''-O-p-hydroxybenzoyl)-β-D-glucoside

maclurin 3-C-(2''-O-p-hydroxybenzoyl-6''-O-galloyl)-β-D-glucoside

maclurin 3-C-(2''-O-galloyl-6''-O-p-hydroxybenzoyl)-β-D-glucoside

maclurin

Downstream raw materials:

mangiferin

4-β-D-glucopyranosyl-1,3-6,7-tetrahydroxy-9H-xanthen-9-one

Refernces

• 1、 Chen, Dawei,Sun, Lili,Chen, Ridao,Xie, Kebo,Yang, Lin,Dai, Jungui. "Enzymatic Synthesis of Acylphloroglucinol 3-C-Glucosides from 2-O-Glucosides using a C-Glycosyltransferase from Mangifera indica". supporting information. p. 5873 - 5877. Retrieved 2016/04/26.
• 2、 Tanaka, Takashi,Sueyasu, Tokiko,Nonaka, Gen-ichiro,Nishioka, Itsuo. "Tannins and Related Compounds. XXI. Isolation and Characterization of Galloyl and p-Hydroxybenzoyl Esters of Benzophenone and Xanthone C-glucosides from Mangifera indica L.". . p. 2676 - 2686. Retrieved 2007/10/02.