Allyltriphenylphosphonium chloride

Base Information

• Chemical Name: Allyltriphenylphosphonium chloride
• CAS No.: 18480-23-4
• Molecular Formula: C21H20P.Cl
• Molecular Weight: 338.817
• Hs Code.: 29310099
• European Community (EC) Number: 242-368-7
• NSC Number: 126440
• DSSTox Substance ID: DTXSID10939897
• Mol file: 18480-23-4.mol

Synonyms:Allyltriphenylphosphonium chloride;18480-23-4;Allyl Triphenylphosphonium Chloride;triphenyl(prop-2-enyl)phosphanium;chloride;EINECS 242-368-7;NSC 126440;triphenyl(prop-2-enyl)phosphonium chloride;Phosphonium, triphenyl-2-propenyl-, chloride;NSC126440;MFCD00031542;triphenyl(prop-2-enyl)phosphanium chloride;triphenyl(prop-2-en-1-yl)phosphanium chloride;C21H20P.Cl;SCHEMBL477383;C21-H20-P.Cl;DTXSID10939897;AKOS015833141;JC10070;NSC-126440;triphenyl(prop-2-enyl)phosphanium,chloride;A1012;CS-0449235;FT-0622016;D88367;A812890;ALLYL TRIPHENYLPHOSPHONIUM CHLORIDE

Chemical Property of Allyltriphenylphosphonium chloride

Chemical Property:

• Appearance/Colour: Beige crystalline powder
• Melting Point: 227-229 °C
• PSA: 13.59000
• LogP: 1.17050
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 338.0991153
• Heavy Atom Count: 23
• Complexity: 284

Purity/Quality:

99% ^*data from raw suppliers

Allyltriphenylphosphonium Chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-]

Technology Process of Allyltriphenylphosphonium chloride

There total 2 articles about Allyltriphenylphosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylphosphine (603-35-0) + 3-chloroprop-1-ene (107-05-1) → allyltriphenylphosphonium chloride (18480-23-4)

Guidance literature:

DOI:10.1021/jo01037a023

Reference yield:

2-Chloroquinoline (612-62-4) + allylidenetriphenylphosphorane (15935-94-1) → allyltriphenylphosphonium chloride (18480-23-4) + 2-[(E)-3-(Triphenyl-λ5-phosphanylidene)-propenyl]-quinoline (54697-94-8)

Guidance literature:

In 1,2-dimethoxyethane;

Reference yield: 86.6%

allyltriphenylphosphonium chloride (18480-23-4) + platinum(II) chloride (10025-65-7) → allyltriphenylphosphonium chloroplatinate(II)

Guidance literature:

In toluene; refluxed for 1 h; solid filtered, washed (toluene and Et2O), air-dried; elem. anal.;

DOI:10.1021/om001034i

upstream raw materials:

triphenylphosphine

3-chloroprop-1-ene

2-Chloroquinoline

allylidenetriphenylphosphorane

Downstream raw materials:

octa-1,3,7-triene

(propenyl)triphenylphosphonium chloride

phenyltriene

Acetic acid 2-prop-2-en-(E)-ylidene-cyclohexyl ester

Refernces

• 1、 Carsky, Petr,Huenig, Siegfried,Stemmler, Ingo,Scheutzow, Dieter. "Two Step Redox Systems, XXVII. - Vinylogous Bipyridyls and Biquinolyls; Syntheses and UV/VIS-Spectra". . p. 291 - 304. Retrieved 2007/10/02.