cobalt triacetate

Base Information

• Chemical Name: cobalt triacetate
• CAS No.: 917-69-1
• Molecular Formula: C₄H₆CoO₄
• Molecular Weight: 177.082
• Mol file: 917-69-1.mol

Synonyms:Aceticacid, cobalt(3+) salt (8CI,9CI); Cobalt acetate (6CI); Cobalt acetate(Co(OAc)3) (7CI); Cobalt triacetate; Cobalt(3+) acetate; Cobalt(III) acetate;Cobaltic acetate

Chemical Property of cobalt triacetate

Chemical Property:

• Melting Point: 99°C (rough estimate)
• PSA: 120.39000
• LogP: -3.73140
• Water Solubility.: soluble H2O with slow hydrolysis, becoming rapid at 60°C–70°C [MER06]

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Catalyst for cumene hydroperoxide decomposition.

Technology Process of cobalt triacetate

There total 46 articles about cobalt triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

cobalt(III) acetate + cyclohexene (110-83-8) → rac-3-acetoxycyclohexene (76644-52-5,76704-31-9,14447-34-8,62247-41-0) + cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7)

Guidance literature:

With potassium bromide; In acetic acid; at 80 ℃; for 1h;

Reference yield:

cobalt(II) diacetate tetrahydrate (6147-53-1) → cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7)

Guidance literature:

In neat (no solvent); byproducts: H2O; heated at different heating rates (0.5, 1, 2, 5, 10 K/ min) to 325-421 K; Kinetics;

DOI:10.1016/0040-6031(89)85463-2

Reference yield:

acetic acid (64-19-7,77671-22-8) → cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7)

Guidance literature:

With cobalt(III) oxide; cobalt; at 120 ℃; under 1520 - 2280 Torr; Eisenautoklav;

upstream raw materials:

acetic anhydride

acetic acid

cyclohexene

cobalt(II) carbonate

Downstream raw materials:

propionic acid

butyric acid

benzoic acid

cobalt(III) acetate

Refernces

• 1、 Hyun, Sung-Min,Yuan, Mingbin,Maity, Asim,Gutierrez, Osvaldo,Powers, David C.. "The Role of Iodanyl Radicals as Critical Chain Carriers in Aerobic Hypervalent Iodine Chemistry". supporting information. p. 2388 - 2404. Retrieved 2019/09/12.
• 2、 Titis,Hudak,Kozisek,Krutosikova,Moncol',Tarabova,Boca. "Structural, spectral and magnetic properties of carboxylato cobalt(II) complexes with heterocyclic N-donor ligands: Reconstruction of magnetic parameters from electronic spectra". . p. 106 - 113. Retrieved 2012/07/14.