4,4'-(Hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenol)

Base Information

• Chemical Name: 4,4'-(Hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenol)
• CAS No.: 1696-60-2
• Molecular Formula: C16H16 N2 O4
• Molecular Weight: 300.314
• Hs Code.: 2928000090
• European Community (EC) Number: 628-732-1
• DSSTox Substance ID: DTXSID201132713
• Mol file: 1696-60-2.mol

Synonyms:4,4'-(Hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenol);1696-60-2;4-[[(4-hydroxy-3-methoxyphenyl)methylidenehydrazinylidene]methyl]-2-methoxyphenol;SCHEMBL591866;DTXSID201132713;FT-0633780;4,4'-(hydrazine-1,2-diylidenebis(methaneylylidene))bis(2-methoxyphenol);4-Hydroxy-3-methoxybenzaldehyde 2-[(4-hydroxy-3-methoxyphenyl)methylene]hydrazone

Chemical Property of 4,4'-(Hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenol)

Chemical Property:

• Vapor Pressure: 6.69E-08mmHg at 25°C
• Melting Point: 179-181 °C(lit.)
• Refractive Index: 1.6240 (estimate)
• Boiling Point: 438.8°Cat760mmHg
• Flash Point: 219.2°C
• PSA: 83.64000
• Density: 1.27g/cm³
• LogP: 2.56800
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 300.11100700
• Heavy Atom Count: 22
• Complexity: 352

Purity/Quality:

99% ^*data from raw suppliers

Vanillin azine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: COC1=C(C=CC(=C1)C=NN=CC2=CC(=C(C=C2)O)OC)O

Technology Process of 4,4'-(Hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenol)

There total 3 articles about 4,4'-(Hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenol) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.6%

vanillin (121-33-5,8014-42-4) → vanillin azine (1696-60-2)

Guidance literature:

With hydrazine hydrate; In ethanol; at 50 ℃;

DOI:10.1039/d0ta01419b

Reference yield:

vanillin (121-33-5,8014-42-4) → vanillin azine (1696-60-2)

Guidance literature:

With ethanol; potassium acetate;

Reference yield:

→ vanillin azine (1696-60-2)

Guidance literature:

Vanillylidenmalonsaeureester, Hydrazin;

upstream raw materials:

vanillin

Downstream raw materials:

vanillin

vanillin thiosemicarbazone

vanillin semicarbazone

Refernces

• 1、 Feng, Jie,Li, Qiong,Liu, Yanlin,Lu, Na,Ma, Songqi,Wang, Sheng,Wu, Jiahui,Xu, Xiwei,Yang, Jintao,Zhu, Jin. "Dihydrazone-based dynamic covalent epoxy networks with high creep resistance, controlled degradability, and intrinsic antibacterial properties from bioresources". . p. 11261 - 11274. Retrieved 2020/06/17.
• 2、 Yatsimirskii, A. K.,Yatsimirskaya, N. T.,Krivova, S. B.. "CONDENSATION OF p-(DIMETHYLAMINO)BENZALDEHYDE WITH HYDRAZINE IN A MICELLAR MEDIUM". . p. 752 - 757. Retrieved 2007/10/02.