Dichlormid

Base Information

• Chemical Name: Dichlormid
• CAS No.: 37764-25-3
• Deprecated CAS: 11140-95-7
• Molecular Formula: C8H11Cl2NO
• Molecular Weight: 208.087
• European Community (EC) Number: 253-658-8
• UNII: E901J4382O
• DSSTox Substance ID: DTXSID4027997
• Nikkaji Number: J20.075A
• Wikidata: Q3026531
• ChEMBL ID: CHEMBL2251310
• Mol file: 37764-25-3.mol

Synonyms:dichlormid;N,N-diallyl-2,2-dichloroacetamide;R 25788;R-25788

Chemical Property of Dichlormid

Chemical Property:

• Appearance/Colour: liquid
• Vapor Pressure: 0.0179mmHg at 25°C
• Melting Point: 5.0-6.5 °C
• Refractive Index: 1.494
• Boiling Point: 253.8 °C at 760 mmHg
• PKA: -1.54±0.70(Predicted)
• Flash Point: 107.3 °C
• PSA: 20.31000
• Density: 1.167 g/cm³
• LogP: 1.99070
• Storage Temp.: 0-6°C
• Water Solubility.: 5g/L(20 oC)
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 207.0217694
• Heavy Atom Count: 12
• Complexity: 170

Purity/Quality:

98% ^*data from raw suppliers

Dichlormid ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 22-23
• Safety Statements: 45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CCN(CC=C)C(=O)C(Cl)Cl
• Uses: Dichlormid is a chemical that in vitro has been shown as a potential herbicide for weed control.

Technology Process of Dichlormid

There total 5 articles about Dichlormid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.7%

chloral (75-87-6) + diallylamine (124-02-7) → N-diallyldichloroacetamide (37764-25-3)

Guidance literature:

With sodium carbonate; 2-hydroxy-2-methylpropanenitrile; In water; at 50 - 55 ℃; for 1h;

DOI:10.1007/BF00777146

Reference yield: 21.0%

N,N-diallyl-α,α,α-trichloroacetamide (39089-57-1) → allidochlor (93-71-0) + N-diallyldichloroacetamide (37764-25-3) + 1-allyl-3-chloro-4-methyl-pyrrolidin-2-one + 3,3-dichloro-4-methyl-1-(2-propenyl)-2-pyrrolidinone

Guidance literature:

With sodium hydroxide; BrMn(CO)5; In dichloromethane; Irradiation;

DOI:10.1016/S0040-4039(02)00323-4

Reference yield:

dichloroacethyl chloride (79-36-7) + diallylamine (124-02-7) → N-diallyldichloroacetamide (37764-25-3)

Guidance literature:

In acetonitrile;

upstream raw materials:

dichloroacethyl chloride

1,2-dichloro-ethane

diallylamine

chloral

Downstream raw materials:

C₃₂H₂₉NO₉S₂

allidochlor

dichloroacetamide

Refernces

• 1、 Huther, Nathalie,McGrail, P.Terry,Parsons, Andrew F.. "Biphasic manganese carbonyl reactions: A new approach to making carbon-carbon bonds". . p. 2535 - 2538. Retrieved 2007/10/03.