Tin(4+);tetrachloride;hydrate

Base Information

• Chemical Name: Tin(4+);tetrachloride;hydrate
• CAS No.: 10026-06-9
• Molecular Formula: Cl₄Sn*6H₂O
• Molecular Weight: 368.614
• Hs Code.: 28273990
• Mol file: 10026-06-9.mol

Synonyms:

Chemical Property of Tin(4+);tetrachloride;hydrate

Chemical Property:

• Appearance/Colour: white solid
• Vapor Pressure: 23.9mmHg at 25°C
• Melting Point: 56 °C
• Boiling Point: 114.1 °C at 760 mmHg
• PSA: 46.15000
• Density: 2.040
• LogP: 2.05570
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 279.785228
• Heavy Atom Count: 6
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Tin(IV) chloride pentahydrate, 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34-52/53
• Safety Statements: 26-36/37/39-45-7/8-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: O.[Cl-].[Cl-].[Cl-].[Cl-].[Sn+4]
• Physical Properties: Colorless fuming liquid; corrosive; density 2.234 g/mL; freezes at –33°C; boils at 114.15°C; critical temperature 318.75°C; critical pressure 37.98 atm; critical volume 351 cm3/mol; soluble in cold water, evolving heat; decomposed by hot water; soluble in alcohol, benzene, toluene, chloroform, acetone and kerosene. The pentahydrate is a yellowish-white crystalline solid or small, fused lumps; faint odor of HCl; density 2.04 g/cm3; decmposes at 56°C; very soluble in water; soluble in ethanol.
• Uses: Tin(IV) chloride is a mordant for dying fabrics; a stabilizer for perfume in soap; used in weighting silk; in ceramic coatings; in manufacturing blue print papers; and to produce fuchsin. Also, tin(IV) chloride is used in preparing many organotin compounds. Substitute for anhydrous stannic chloride where the presence of water is not objectionable Tin (IV) Chloride Pentahydrate is a hydrate of Tin (IV) Chloride(T443805), which can induce slight inhibition of the catalytic activity of horse liver alcohol dehydrogenase (HLADH).

Technology Process of Tin(4+);tetrachloride;hydrate

There total 18 articles about Tin(4+);tetrachloride;hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

2-(2-acetoxy-5-methylphenyl)-4,6-dimethyl-1-benzopyranylium pentachlorostannate → (acetoxy-2-methyl-5-phenyl)-2-dimethyl-4,6-benzopyranne-1-ylium hexachlorostannate + stannic tetrachloride pentahydrate (152598-97-5,16523-10-7,10026-06-9) + (acetoxy-2-methyl-5-phenyl)-2-methylidene-4-methyl-6-4H-benzopyranne-1

Guidance literature:

With H₂O; In neat (no solvent); stirring at 20°C, 7 d, filtration; sublimation of SnCl4*H2O (45°C/10 Torr), filtration, treatment of the residue with acetone, leaving pure Sn complex, chromy. (silica gel)and recrystn. (CHCl3) to obtain the benzopyran, elem.anal.;

DOI:10.1002/hlca.19880710416

Reference yield:

tin(II) chloride dihdyrate (10025-69-1) + iron(III) oxalate pentahydrate → tin(IV) chloride tetrahydrate (10026-06-9) + Sn(2+)*C2O4(2-)*3H2O=SnC2O4*3H2O + FeC2O4, α (516-03-0)

Guidance literature:

In neat (no solvent, solid phase); Solid state reaction in hydrogen or helium atmosphere.; Gas chromatography, Moessbauer spectroscopy.;

DOI:10.1016/0040-6031(88)87249-6

Reference yield:

tin(IV) chloride * 2 sulfur tetrachloride → hydrogenchloride (7647-01-0,15364-23-5) + tin(IV) chloride hydrate (10026-06-9) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3)

Guidance literature:

With air; In neat (no solvent); fuming in air with decompn.;;

upstream raw materials:

tin(IV) chloride

water

chlorine

hydrogenchloride

Downstream raw materials:

bis(toluene-3,4-dithiolato)tin(IV)

Refernces

• 1、 Jolibois, Henri,Theobald, Francois,Vebrel, Joel,Guyetant, Rene. "Synthesis and Characterization of a New Class of Flavylium Salts; a Facile Route to the 2-(2-Acetoxyphenyl)-4-methylidene-4H-1-benzopyran Derivatives. X-Ray Crystal Structure of 2-(2-Acetoxy-5-methylphenyl)-4,6-dimethyl-1-benzopyranylium Pentachlorostannate: Supporting Evidence of Chl...". . p. 812 - 817. Retrieved 2007/10/02.