TRIBUTYLTIN FLUORIDE POLYMER

Base Information

• Chemical Name: TRIBUTYLTIN FLUORIDE POLYMER
• CAS No.: 27615-98-1
• Molecular Formula: C12H27FSn
• Molecular Weight: 309.0511832
• Mol file: 27615-98-1.mol

Synonyms:Stannane, tributylfluoro-, polymers

Chemical Property of TRIBUTYLTIN FLUORIDE POLYMER

Chemical Property:

• Vapor Pressure: 0.0135mmHg at 25°C
• Melting Point: 269-271 °C(lit.)
• Boiling Point: 267.3°C at 760 mmHg
• Flash Point: 115.5°C
• Density: 1.280

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 35-36/37/39-45-60-61

MSDS Files:

Useful:

Technology Process of TRIBUTYLTIN FLUORIDE POLYMER

There total 25 articles about TRIBUTYLTIN FLUORIDE POLYMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pivaloyl fluoride (1478-62-2) + tributyltin methoxide (1067-52-3) → tributyltin fluoride (1983-10-4,27615-98-1)

Guidance literature:

0°C; <1 min;

DOI:10.1016/S0022-328X(00)82592-9

Reference yield: 91.0%

(pentamethylcyclopentadienyl)titanium fluoride + bis(tri-n-butyltin)oxide (56-35-9) → (C5(CH3)5TiF(O))4 + tributyltin fluoride (1983-10-4,27615-98-1)

Guidance literature:

In toluene; dropping O(SnBu3)2 in toluene to (C5Me5)TiF3 in toluene under stirring; removal of FSnBu3 by filtration after 12 h, removal of the solvent from the filtrate in vacuo and recrystn. of the residue from n-hexane, elem. anal.;

Reference yield: 87.0%

tributylphenylstannane (960-16-7) + cesium fluoride (13400-13-0) → tributyltin fluoride (1983-10-4,27615-98-1)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; bromobenzene; lithium chloride; In N,N-dimethyl-formamide; at 110 ℃; for 12h; Reagent/catalyst; Inert atmosphere;

upstream raw materials:

1,3,5-Trioxan

Tributyl-((E)-4-phenyl-but-2-enyl)-stannane

(E)-1-tri-n-butylstannyl-2-undecene

1-bromo-hexane

Downstream raw materials:

[Zr(C₆F₅NCH₂CH₂OCH₂CH₂OCH₂CH₂NC₆F₅)(F)]2F₂

benzyltributyltin

(E)-3-(tri-n-butylstannyl)-2-propen-1-ol

2-(tributylstannyl)prop-2-en-1-ol

Refernces

• 1、 -. "Organic tin compound cycle application Stille method of synthesis of biphenyl". Paragraph 0051; 0053-0054. . Retrieved 2017/05/12.
• 2、 Ballivet-Tkatchenko,Douteau,Stutzmann. "Reactivity of carbon dioxide with n-butyl(phenoxy)-,(alkoxy)-, and (oxo)stannanes: insight into dimethyl carbonate synthesis". . p. 4563 - 4567. Retrieved 2008/10/08.