INSECTICIDE

Base Information

• Chemical Name: INSECTICIDE
• CAS No.: 174060-41-4
• Molecular Formula: C22H17ClF3N3O7
• Molecular Weight: 527.8344896
• Mol file: 174060-41-4.mol

Synonyms:INSECTICIDE;ASSAIL 70 WP;AVATAR;AVAUNT 150;INTRUDER;LANNATE BR;LANNATE SP;METHOMYL TECHNICAL

Chemical Property of INSECTICIDE

Chemical Property:

• PSA: 106.97000
• LogP: 3.46680

Purity/Quality:

98% or more ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of INSECTICIDE

There total 12 articles about INSECTICIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.8%

methyl 7-chloro-2,3,4a,5-tetrahydro-2-[methoxycarbonyl(4-trifluoromethoxyphenyl)carbamoyl]-indeno[1,2-e][1,3,4]oxadiazine-4a-carboxylate (144171-61-9,173584-44-6,174060-41-4) → indoxacarb (144171-61-9,173584-44-6,174060-41-4)

Guidance literature:

With chiral column; In methanol; Petroleum ether; at -10 - 65 ℃; for 15h; Solvent; Temperature; Resolution of racemate;

Reference yield: 94.8%

chloroformyl(4-trifluoromethoxyphenyl)carbamic acid methyl ester (173903-15-6) + C12H11ClN2O3 (173903-23-6) → methyl 7-chloro-2,3,4a,5-tetrahydro-2-[methoxycarbonyl(4-trifluoromethoxyphenyl)carbamoyl]-indeno[1,2-e][1,3,4]oxadiazine-4a-carboxylate (144171-61-9,173584-44-6,174060-41-4)

Guidance literature:

With sodium hydroxide; In toluene; at 25 - 30 ℃; for 2h;

Reference yield: 75.8%

chloroformyl(4-trifluoromethoxyphenyl)carbamic acid methyl ester (173903-15-6) + C27H21ClN2O5 → (S)-methyl-7-chloro-2,3,4a,5-tetrahydro-2-[methoxycarbonyl(4-trifluoromethoxyphenyl)aminoformyl]indeno[1,2-e][1,3,4]oxadiazine-4a-carboxylate (144171-61-9,173584-44-6,174060-41-4)

Guidance literature:

With piperidine; at 15 ℃; Inert atmosphere;

DOI:10.1002/jhet.2449

upstream raw materials:

methyl 7-chloro-2,3,4a,5-tetrahydro-2-[methoxycarbonyl(4-trifluoromethoxyphenyl)carbamoyl]-indeno[1,2-e][1,3,4]oxadiazine-4a-carboxylate

chloroformyl(4-trifluoromethoxyphenyl)carbamic acid methyl ester

methyl chloroformate

4-(trifluoromethoxy)aniline

Downstream raw materials:

indoxacarb

(S)-methyl-7-chloro-2,3,4a,5-tetrahydro-2-[methoxycarbonyl(4-trifluoromethoxyphenyl)aminoformyl]indeno[1,2-e][1,3,4]oxadiazine-4a-carboxylate

Refernces

• 1、 -. "CRYSTALLINE FORM OF INDOXACARB, PROCESS FOR ITS PREPARATION AND USE THEREOF". Paragraph 0070. . Retrieved 2018/09/02.