RuPhos Pd G3

Base Information

• Chemical Name: RuPhos Pd G3
• CAS No.: 1445085-77-7
• Molecular Formula: C₁₃H₁₃NO₃PdS*C₃₀H₄₃O₂P
• Molecular Weight: 836.381
• Mol file: 1445085-77-7.mol

Synonyms:Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [RuPhos Palladacycle];Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%;RuPhos Pd G3 95%;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);(2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate;RuPhos Pd G3;RuPhos-G3-Palladacycle;RuPhos-Pd-G3

Chemical Property of RuPhos Pd G3

Chemical Property:

• Melting Point: 188-196°C (decomposition)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

98% ^*data from raw suppliers

Methanesulfonato(2-dicyclohexylphosphino-2'',6''-di-i-propoxy-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38-52/53
• Safety Statements: 26-61

MSDS Files:

Useful:

• Uses: RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.Suzuki-Miyaura-cross-coupling of aminothiophenes.

Technology Process of RuPhos Pd G3

There total 3 articles about RuPhos Pd G3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer (1435520-65-2) + ruphos (787618-22-8) → C30H43O2P*C13H13NO3PdS (1445085-77-7)

Guidance literature:

In tetrahydrofuran; at 20 ℃;

DOI:10.1039/c2sc20903a

Reference yield:

2-phenylaniline (90-41-5) → C30H43O2P*C13H13NO3PdS (1445085-77-7)

Guidance literature:

Multi-step reaction with 3 steps

1: Isopropyl acetate / 20 °C

2: toluene / 65 °C

3: tetrahydrofuran / 20 °C

In tetrahydrofuran; Isopropyl acetate; toluene;

DOI:10.1039/c2sc20903a

Reference yield:

[1,1'-biphenyl]-2-aminium methanesulfonate (1445085-50-6) → C30H43O2P*C13H13NO3PdS (1445085-77-7)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene / 65 °C

2: tetrahydrofuran / 20 °C

In tetrahydrofuran; toluene;

DOI:10.1039/c2sc20903a

upstream raw materials:

2-phenylaniline

[1,1'-biphenyl]-2-aminium methanesulfonate

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer

ruphos

Refernces