Dideuteriomethanone

Base Information

• Chemical Name: Dideuteriomethanone
• CAS No.: 1664-98-8
• Molecular Formula: CD2 O
• Molecular Weight: 32.0104
• Hs Code.: 28459000
• European Community (EC) Number: 216-775-5,686-130-4
• DSSTox Substance ID: DTXSID00168098
• Nikkaji Number: J195.302H
• Wikidata: Q83037604
• Mol file: 1664-98-8.mol

Synonyms:dideuteriomethanone;Paraformaldehyde-d2;1664-98-8;(2H)Formaldehyde;Formaldehyde-d2;32008-59-6;CD2O;Formaldehyde-d2 (6CI,8CI,9CI);EINECS 216-775-5;Formaldehyde-d2-;(2H2)Formaldehyde;C-D2-O;DTXSID00168098;Formaldehyde-d2 (~20% in D2O);MFCD00145070;AT37380;Formaldehyde-d2 (~20per cent in D2O);J-010288;J-018598;FORMALIN-D2 (20% W/W IN H2O) 99 ATOM % D

Chemical Property of Dideuteriomethanone

Chemical Property:

• Vapor Pressure: 3460mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 17.07000
• Density: 0.684g/cm³
• LogP: 0.45100
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 32.023118175
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Formaldehyde-d2 ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,C
• Statements: 20/21/22-36/37/38-40-43-34
• Safety Statements: 26-36/37-51-45-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=O
• Isomeric SMILES: [2H]C(=O)[2H]
• Uses: (Formaldehyde-D2) Labelled Formaldehyde, used in various organic synthesis and reactions. It is used in the textile industry in the area of crosslinking molecules to vary the properties of fabrics. In the food industry it is used to reinforce and improve packaging of meats and produce. It can help improve the water resistance of biodegradable collagen films. Formalin-d2 (20% w/w in H2O) can be used for labeling protein by alkylation, enzymolysis and isotope labeling. Stable Isotope methyl labeling has led to quantification of antigens in influenza vaccine. It is also used in global antigen quantification of different types of protein-based vaccine and manufacturing intermediates.

Technology Process of Dideuteriomethanone

There total 50 articles about Dideuteriomethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

<2H2>methylene diacetate (22117-87-9) → paraformaldehyde-d2 (1664-98-8,43094-80-0)

Guidance literature:

With hydrogenchloride; In water; for 17h; Heating;

Reference yield: 15.0%

→ paraformaldehyde-d2 (1664-98-8,43094-80-0) + bis[2-(2-pyridyl)ethyl]amine (15496-36-3) + C15H17(2)H2N3 + C22H23(2)H2N3O

Guidance literature:

With oxygen; In dichloromethane; at 0 ℃; for 24h;

DOI:10.1021/ja00033a024

Reference yield:

methanol (67-56-1) + methane (558-20-3) + oxygen (80937-33-3) + chlorine (7782-50-5) → paraformaldehyde-d2 (1664-98-8,43094-80-0) + water (14940-63-7) + methyl-d3 peroxy radical + hydroperoxyl radical (7782-44-7) + methyl-d3 hydroperoxide

Guidance literature:

In gas; byproducts: HCl, DCl, CH2O; Irradiation (UV/VIS); near-u.v. modulated photolysis of flowing Cl2-CD4-CH3OH-O2 mixtures, 10.8 Torr, 300K, Pyrex react. vessel; Kinetics;

DOI:10.1039/F29888400913

upstream raw materials:

dihydroxyfumaric acid

formaldehyd

diazomethane-d2

perdeuterioallene

Downstream raw materials:

C₁₃H₂₁⁽²⁾H₂NOSi

4-Hydroxy-6-methyl-3-phenylthio<2H2>methyl-2H-pyran-2-one

dideuterioformic acid

C⁽²⁾H₂O₃

Refernces

• 1、 Wang, Qinggen,Biener, Jurgen,Guo, Xing-Cai,Farfan-Arribas, Enrique,Madix, Robert J.. "Reactivity of stoichiometric and defective TiO2 (110) surfaces toward DCOOD decomposition". . p. 11709 - 11720. Retrieved 2003.
• 2、 Shiragami, Tsutomu,Kuroki, Ayano,Matsumoto, Jin,Yasuda, Masahide. "C-H bond activation with Ge-oxyl complex generated by photoinduced- electron-transfer of di(hydroxo)porphyrin GeIV complex". . p. 529 - 534. Retrieved 2014.
• 3、 Ebers,Nielsen. "". . p. 311. Retrieved 1938.
• 4、 Mesa, Camilo A.,Kafizas, Andreas,Francàs, Laia,Pendlebury, Stephanie R.,Pastor, Ernest,Ma, Yimeng,Le Formal, Florian,Mayer, Matthew T.,Gr?tzel, Michael,Durrant, James R.. "Kinetics of Photoelectrochemical Oxidation of Methanol on Hematite Photoanodes". . p. 11537 - 11543. Retrieved 2017.
• 5、 Bai, Hebi,Ault, Bruce S.. "Matrix Isolation Investigation of the Room Temperature and Pyrolytic Reactions of (CH3)2Zn with CH3OH and CH3SH". . p. 10492 - 10497. Retrieved 1995.
• 6、 Nesbitt, F. L.,Payne, W. A.,Stief, L. J.. "Kinetic Studies of the Reaction of the Hydroxymethyl Radical with NO and NO2". . p. 5158 - 5161. Retrieved 1989.
• 7、 Zhao, Yan-Xia,Li, Zi-Yu,Yuan, Zhen,Li, Xiao-Na,He, Sheng-Gui. "Thermal methane conversion to formaldehyde promoted by single platinum atoms in PtAl2O4- cluster anions". . p. 9482 - 9486. Retrieved 2014.
• 8、 Jana, Sandipan,Thomas, Jithin,Sen Gupta, Sayam. "Catalytic oxidation of alcohols using Fe-bTAML and NaClO: Comparing the reactivity of Fe(V)O and Fe(IV)O intermediates". supporting information. p. 476 - 482. Retrieved 2018/11/23.
• 9、 Rauch, Michael,Strater, Zack,Parkin, Gerard. "Selective Conversion of Carbon Dioxide to Formaldehyde via a Bis(silyl)acetal: Incorporation of Isotopically Labeled C1 Moieties Derived from Carbon Dioxide into Organic Molecules". supporting information. p. 17754 - 17762. Retrieved 2019/11/05.