Technology Process of 3-n-Undecylthiophene
There total 2 articles about 3-n-Undecylthiophene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
pyridine N-oxide; [2,2]bipyridinyl; potassium fluoride; lithium chloride; nickel dichloride; zinc;
In
N,N-dimethyl acetamide;
at 0 - 25 ℃;
for 24h;
DOI:10.1021/acscatal.8b03396
- Guidance literature:
-
With
1,3-bis[(diphenylphosphino)propane]dichloronickel(II);
In
tetrahydrofuran;
for 15h;
Reflux;
DOI:10.1039/c3sc50664a
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: N-Bromosuccinimide / tetrahydrofuran / 15 h / 25 °C
2.1: magnesium / tetrahydrofuran / 0.5 h / Reflux
2.2: 15 h / Reflux
3.1: boron tribromide / dichloromethane / 24 h / -78 - 25 °C
4.1: potassium carbonate / acetonitrile / 6 h / Reflux
5.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 25 °C
6.1: pyridinium p-toluenesulfonate; toluene-4-sulfonic acid / 24 h / 25 °C
7.1: n-butyllithium; copper dichloride / tetrahydrofuran / 15 h / -60 °C / Reflux
8.1: hydrogenchloride / water; methanol / 24 h / 25 °C
With
hydrogenchloride; N-Bromosuccinimide; osmium(VIII) oxide; n-butyllithium; pyridinium p-toluenesulfonate; boron tribromide; potassium carbonate; toluene-4-sulfonic acid; magnesium; 4-methylmorpholine N-oxide; copper dichloride;
In
tetrahydrofuran; methanol; dichloromethane; water; acetone; acetonitrile;
2.2: |Kumada Cross-Coupling;
DOI:10.1039/c3sc50664a
