O,P'-Methoxychlor

Base Information

• Chemical Name: O,P'-Methoxychlor
• CAS No.: 30667-99-3
• Molecular Formula: C16H15 Cl3 O2
• Molecular Weight: 345.65
• Hs Code.: 2909309090
• NSC Number: 123014
• UNII: 0Z8MDD38HB
• DSSTox Substance ID: DTXSID1042231
• Nikkaji Number: J124.984C
• Wikidata: Q27894630
• Mol file: 30667-99-3.mol

Synonyms:O,P'-METHOXYCHLOR;2,4'-METHOXYCHLOR;30667-99-3;o,p-Methoxychlor;0Z8MDD38HB;1-Methoxy-2-[2,2,2-trichloro-1-(4-methoxyphenyl)ethyl]benzene;NSC 123014;NSC-123014;AI3-16095;Ethane, 1,1,1-trichloro-2-(o-methoxyphenyl)-2-(p-methoxyphenyl)-;Benzene, 1-methoxy-2-[2,2,2-trichloro-1-(4-methoxyphenyl)ethyl]-;Benzene, 1-methoxy-2-(2,2,2-trichloro-1-(4-methoxyphenyl)ethyl)-;1-METHOXY-2-(2,2,2-TRICHLORO-1-(4-METHOXYPHENYL)ETHYL)BENZENE;O,P/'-Methoxychlor;UNII-0Z8MDD38HB;DTXSID1042231;KNLLPAOBVIKLDE-UHFFFAOYSA-N;NSC123014;O,P'-METHOXYCHLOR, (+/-)-;Benzene,2,2-trichloro-1-(4-methoxyphenyl)ethyl]-;Q27894630;Ethane,1,1-trichloro-2-(o-methoxyphenyl)-2-(p-methoxyphenyl)-;1-Methoxy-2-[2,2,2-trichloro-1-(4-methoxyphenyl)ethyl]benzene #;1-methoxy-2-[2,2,2-trichloro-1-(4methoxyphenyl) ethyl]-benzene;Benzene, 1-methoxy-2-(2,2,2-trichloro-1-(4-methoxyphenyl)ethyl)- (9CI)

Chemical Property of O,P'-Methoxychlor

Chemical Property:

• Vapor Pressure: 1.69E-07mmHg at 25°C
• Melting Point: 79.5-80 °C(Solv: ethanol (64-17-5))
• Boiling Point: 439.1°Cat760mmHg
• Flash Point: 150.8°C
• PSA: 18.46000
• Density: 1.288g/cm³
• LogP: 5.20590
• Storage Temp.: APPROX 4°C
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 344.013763
• Heavy Atom Count: 21
• Complexity: 311

Purity/Quality:

99%min ^*data from raw suppliers

2,4''-Methoxychlor ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,T
• Statements: 11-23/24/25-39/23/24/25
• Safety Statements: 7-16-36/37-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C(C2=CC=CC=C2OC)C(Cl)(Cl)Cl
• Uses: 2,4'-Methoxychlor, is asymmetrical analogues of Methoxychlor, which is a synthetic organochlorine used as an insecticide. It is used to protect crops, ornamentals, livestock, and pets against fleas, mosquitoes, cockroaches, and other insects. 2,4''-Methoxychlor, is asymmetrical analogues of Methoxychlor, which is a synthetic organochlorine used as an insecticide. It is used to protect crops, ornamentals, livestock, and pets against fleas, mosquitoes, cockroaches, and other insects.

Technology Process of O,P'-Methoxychlor

There total 4 articles about O,P'-Methoxychlor which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methoxy-α-(trichloromethyl)benzyl alcohol (58369-59-8) + methoxybenzene (100-66-3) → 1,1,1-trichloro-2-(2-methoxyphenyl)-2-(4-methoxyphenyl)ethane (30667-99-3)

Guidance literature:

With sulfuric acid; acetic acid; at 0 ℃;

DOI:10.1021/ja01176a087

Reference yield:

4-methoxyphenyl magnesium bromide (13139-86-1) → 1,1,1-trichloro-2-(2-methoxyphenyl)-2-(4-methoxyphenyl)ethane (30667-99-3)

Guidance literature:

Multi-step reaction with 2 steps

2: concentrated sulfuric acid; glacial acetic acid / 0 °C

With sulfuric acid; acetic acid;

DOI:10.1021/ja01176a087

Reference yield:

ortho-anisaldehyde (135-02-4) → 1,1,1-trichloro-2-(2-methoxyphenyl)-2-(4-methoxyphenyl)ethane (30667-99-3)

Guidance literature:

Multi-step reaction with 2 steps

1: KOH

2: H₂SO₄

With potassium hydroxide; sulfuric acid;

DOI:10.1021/jm00232a014

upstream raw materials:

2-methoxy-α-(trichloromethyl)benzyl alcohol

methoxybenzene

sulfuric acid

acetic acid

Downstream raw materials:

1,1-dichloro-2-(2-methoxyphenyl)-2-(4-methoxyphenyl)ethene

1,1,1-trichloro-2-(2-methoxy-3,5-dinitro-phenyl)-2-(4-methoxy-3,5-dinitro-phenyl)-ethane