Polyglycerine

Base Information

• Chemical Name: Polyglycerine
• CAS No.: 25618-55-7
• Molecular Formula: (C3H8O3)x
• Molecular Weight: 92.09380
• Hs Code.: 3907200000
• Mol file: 25618-55-7.mol

Synonyms:Glycerin homopolymer;Glycerol homopolymer;Glycerol polymer;HL 80;K-COL-IV 500;PG 06 (homopolymer);1,2,3-Propanetriol,homopolymer;Polyglycerin;Polyglycerin 801;Polyglycerin K;PolyglycerinK-COL-IV 750;

Chemical Property of Polyglycerine

Chemical Property:

• Appearance/Colour: Liquid
• Vapor Pressure: 0.000232mmHg at 25°C
• Melting Point: 20oC
• Refractive Index: 1.4955
• Boiling Point: 290 °C
• Flash Point: 156 °C
• PSA: 60.69000
• Density: 1.2892
• LogP: -1.66810

Purity/Quality:

99.9% ^*data from raw suppliers

Polyglycerine(TechnicalGrade) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Polyglycerine

There total 598 articles about Polyglycerine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

D-sorbitol (50-70-4) → tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + TETRAHYDROPYRANE (142-68-7) + 2-methyltetrahydrofuran (96-47-9) + 2,5-dimethyltetrahydrofuran (1003-38-9) + methanol (67-56-1) + propan-1-ol (71-23-8) + 2-Methylcyclopentanone (1120-72-5) + 3-methyl-cyclopentanone (1757-42-2,6195-92-2) + propylene glycol (57-55-6,63625-56-9) + ethanol (64-17-5) + n-hexan-3-ol (623-37-0) + 2-methylpentan-1-ol (105-30-6) + (S)-Ethyl lactate (687-47-8) + pentan-1-ol (71-41-0) + vinyl formate (692-45-5) + n-hexan-2-one (591-78-6) + n-hexan-3-one (589-38-8) + Isopropyl acetate (108-21-4) + 3-Hydroxy-2-pentanone (3142-66-3,113919-08-7) + acetic acid (64-19-7,77671-22-8) + propionaldehyde (123-38-6) + 2-Pentanone (107-87-9) + propionic acid (802294-64-0,79-09-4) + 1-Hydroxy-2-butanone (5077-67-8) + 2,5-hexanedione (110-13-4) + isopropyl alcohol (67-63-0,8013-70-5) + acetone (67-64-1) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) + pentan-3-one (96-22-0) + isobutyric Acid (79-31-2) + butanone (78-93-3) + iso-butanol (78-92-2,15892-23-6) + hexanoic acid (142-62-1) + Isosorbide (652-67-5) + butyric acid (107-92-6) + 2.3-butanediol (513-85-9) + hexan-1-ol (111-27-3) + valeric acid (109-52-4)

Guidance literature:

platinum on carbon; In water; for 3h; Direct aqueous phase reforming;

Reference yield:

2-phenyl-[1,3]dioxan-5-ol (1708-40-3) → benzaldehyde (100-52-7) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0)

Guidance literature:

With iron(II) triflate; bis[(2-pyridyl)methyl]amine;

DOI:10.1016/j.molcata.2014.10.021

Reference yield:

sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4) → propylene glycol (57-55-6,63625-56-9) + 1,2,3,4-butanetetrol (2319-57-5,2418-52-2,6968-16-7,7493-90-5,7541-59-5,10030-58-7,188346-77-2,149-32-6) + ethylene glycol (107-21-1) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0)

Guidance literature:

With palladium on activated charcoal; hydrogen; at 240 ℃; for 24h;

DOI:10.1016/j.mcat.2017.12.038

upstream raw materials:

diazomethane

methanol

triacetylglycerol

formaldehyd

Downstream raw materials:

1,5-naphthyridine

2-phenyl-1⁽³⁾H-imidazo[4,5-f]quinoline

1,2,3-tris-(3-nitro-benzoyloxy)-propane

2-amino-1,5-naphthyridine

Refernces

• 1、 De Rosa,M.,De Rosa,S.. "-". . p. 249. Retrieved 1980.
• 2、 El Kadib, Abdelkrim,Chimenton, Ricardo,Sachse, Alexander,Fajula, Francois,Galarneau, Anne,Coq, Bernard. "Functionalized inorganic monolithic microreactors for high productivity in fine chemicals catalytic synthesis". . p. 4969 - 4972. Retrieved 2009.
• 3、 Zerner. "-". . p. 326. Retrieved 1920.
• 4、 Ostwald. "-". . p. 279. Retrieved 1919.
• 5、 Cormier. "Removal of TBDMS protecting groups from carbohydrates using catalytic transfer hydrogenation". . p. 187 - 188. Retrieved 1991.
• 6、 Schwaighofer, Andreas,Akhgar, Christopher K.,Lendl, Bernhard. "Broadband laser-based mid-IR spectroscopy for analysis of proteins and monitoring of enzyme activity". . . Retrieved 2021.
• 7、 Neuberg,Hirsch. "-". . . Retrieved 1919.
• 8、 Rakhmanberdyeva,Shashkov,Bobakulov, Kh.M.,Azizov,Malikova, M.Kh.,Ogay. "The structure and prebiotic activity of arabinogalactan from Ferula Kuhistаnica". . . Retrieved 2021.
• 9、 Wang, Yu,Tao, Fei,Ni, Jun,Li, Chao,Xu, Ping. "Production of C3 platform chemicals from CO2 by genetically engineered cyanobacteria". . p. 3100 - 3110. Retrieved 2015.
• 10、 Li, Xiaoxun,Livant, Peter D.,Chen, Jianjun. "An Alkene-Forming Cascade Reaction en Route to 2,2'-Bi(glycerol)". . p. 1769 - 1772. Retrieved 2018.