Germane, trimethyl(phenylthio)-

Base Information

• Chemical Name: Germane, trimethyl(phenylthio)-
• CAS No.: 4848-62-8
• Molecular Formula: C9H14GeS-
• Molecular Weight: 226.866
• DSSTox Substance ID: DTXSID90197534
• Nikkaji Number: J342.085J
• Wikidata: Q83070380
• Mol file: 4848-62-8.mol

Synonyms:Germane, trimethyl(phenylthio)-;4848-62-8;Trimethyl(phenylthio)germane;Germane,trimethyl(phenylthio)-;DTXSID90197534

Chemical Property of Germane, trimethyl(phenylthio)-

Chemical Property:

• Boiling Point: 169.1°Cat760mmHg
• Flash Point: 50.6°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 228.0027994
• Heavy Atom Count: 11
• Complexity: 111

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Ge](C)(C)SC1=CC=CC=C1

Technology Process of Germane, trimethyl(phenylthio)-

There total 4 articles about Germane, trimethyl(phenylthio)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

chlorotrimethylgermane (1529-47-1) + bis(benzenethiolato)lead(II) (32812-89-8) → Trimethyl(phenylthio)germane (4848-62-8)

Guidance literature:

In tetrahydrofuran; suspended Pb(SPh)2 and Me3GeCl in THF, refluxed with stirring under inert gas; filtered, evapd., distd. in vac.;

Reference yield: 71.0%

bis(trimethylgermyl)carbodiimide (59579-33-8) + thiophenol (108-98-5) → (H2NCN)2 + Trimethyl(phenylthio)germane (4848-62-8)

Guidance literature:

In neat (no solvent); excess of thiol, room temp., 60 min; evapn. of excess thiol (-45°C, pumping), distn.;

DOI:10.1039/DT9760000366

Reference yield:

trimethylbromogermane (1066-37-1) + thiophenol (108-98-5) → Trimethyl(phenylthio)germane (4848-62-8)

Guidance literature:

With triethylamine; In chloroform; to CHCl3 soln. of Me3GeBr and Et3N PhSH added, refluxed for 2 h; evapd., hexane added to ppt. amine salt, evapd., distd.;

upstream raw materials:

chlorotrimethylgermane

bis(benzenethiolato)lead(II)

trimethylbromogermane

thiophenol

Downstream raw materials:

isopropylthiobenzene

iodotrimethylgermane

[(1-phenylethyl)thio]benzene

chlorotrimethylgermane

Refernces