Dodecyl acrylate

Base Information

• Chemical Name: Dodecyl acrylate
• CAS No.: 2156-97-0
• Deprecated CAS: 199685-42-2,885007-57-8,1418209-80-9,1887074-73-8,885007-57-8
• Molecular Formula: C15H28O2
• Molecular Weight: 240.386
• Hs Code.: 29161290
• European Community (EC) Number: 218-463-4
• NSC Number: 24177
• UNII: 90IK36WGVR
• DSSTox Substance ID: DTXSID7022178
• Nikkaji Number: J107.540C
• Wikidata: Q27271326
• Mol file: 2156-97-0.mol

Synonyms:Dodecyl acrylate;2156-97-0;Lauryl acrylate;dodecyl prop-2-enoate;n-Lauryl acrylate;n-Dodecyl acrylate;2-Propenoic acid, dodecyl ester;Acrylic acid, dodecyl ester;NSC 24177;Acrylic Acid Lauryl Ester;Acrylic Acid Dodecyl Ester;90IK36WGVR;C15H28O2;EINECS 218-463-4;NSC-24177;AI3-03198;dodecyl propenoate;Ageflex FA-12;Acrylic acid-dodecyl ester;LIGHT ACRYLATE L-A;UNII-90IK36WGVR;PHOTOMER 4812;N-Lauryl acrylate (monomer);SCHEMBL14939;2-propenoic acid dodecyl ester;LAURYL ACRYLATE [INCI];DTXSID7022178;CHEBI:191951;2-Propenoic acid, n-dodecyl ester;CAA15697;NSC24177;MFCD00042871;SR 335;AKOS015916172;Lauryl acrylate, technical grade, 90%;Dodecyl Acrylate (stabilized with MEHQ);LS-184918;D4129;FT-0627726;EC 218-463-4;F20309;A815489;W-107541;Q27271326

Chemical Property of Dodecyl acrylate

Chemical Property:

• Vapor Pressure: 0.000784mmHg at 25°C
• Melting Point: 4oC
• Refractive Index: n20/D 1.445(lit.)
• Boiling Point: 306.2 °C at 760 mmHg
• Flash Point: 110.4 °C
• PSA: 26.30000
• Density: 0.875 g/cm³
• LogP: 4.63650
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: 1μg/L at 20℃
• XLogP3: 6.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 240.208930132
• Heavy Atom Count: 17
• Complexity: 187

Purity/Quality:

99.9% ^*data from raw suppliers

Dodecyl Acrylate (stabilized with MEHQ) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi, N
• Hazard Codes: Xi,N
• Statements: 36/37/38-51/53
• Safety Statements: 26-28-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCCCCCOC(=O)C=C
• Uses: Lauryl acrylate can undergo atom transfer radical polymerization (ATRP) to form its polymer. Lauryl acrylate may undergo photoinitiated polymerization in the presence of N-acetyl-4-nitro-1-naphthylamine (ANNA) and N,N-dimethylaniline (DMA).

Technology Process of Dodecyl acrylate

There total 13 articles about Dodecyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.8%

1-dodecyl alcohol (112-53-8) + acrylic acid (79-10-7) → lauryl acrylate (2156-97-0)

Guidance literature:

With 10H-phenothiazine; hydroquinone; at 110 - 130 ℃; for 4h;

Reference yield: 84.0%

1-dodecyl alcohol (112-53-8) + acryloyl chloride (814-68-6,25189-84-8) → lauryl acrylate (2156-97-0)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 10 - 20 ℃; for 3h;

DOI:10.1016/j.ijpharm.2011.05.006

Reference yield: 70.0%

1-dodecyl alcohol (112-53-8) + acryloyl-1,3-oxazolidin-2-one (2043-21-2) → lauryl acrylate (2156-97-0)

Guidance literature:

With ytterbium(III) triflate; In acetonitrile; at 90 ℃; for 48h; Sealed tube; Inert atmosphere;

DOI:10.1021/acs.orglett.8b01896

upstream raw materials:

1-dodecyl alcohol

acrylic acid methyl ester

acetylene

Acrylic acid 12-iodo-dodecyl ester

Downstream raw materials:

1-dodecyl propionate

biphenyl-2,3-dicarboxylic acid dimethyl ester

trans-dodecyl-3-phenylprop-2-enoate

C₂₆H₄₁NO₄

Refernces

• 1、 Liu, Gang,Song, Shanshan,Liu, Xiaohua,Zhang, Ao,Miao, Zehong,Ding, Chunyong. "Novel dihydroisoxazoline-alkyl carbon chain hybrid artemisinin analogues (artemalogs): Synthesis and antitumor activities". . p. 98975 - 98984. Retrieved 2016.
• 2、 -. "Efficient metal-containing cationic antitumor drug as well as preparation method and application thereof". Paragraph 0053-0054. . Retrieved 2021/06/26.
• 3、 Park, Kwihwan,Matsuda, Takumi,Yamada, Tsuyoshi,Monguchi, Yasunari,Sawama, Yuka,Doi, Naoki,Sasai, Yasushi,Kondo, Shin-Ichi,Sawama, Yoshinari,Sajiki, Hironao. "Direct Deuteration of Acrylic and Methacrylic Acid Derivatives Catalyzed by Platinum on Carbon in Deuterium Oxide". supporting information. p. 2303 - 2307. Retrieved 2018/05/07.