NITRIC ACID-D

Base Information

• Chemical Name: NITRIC ACID-D
• CAS No.: 13587-52-5
• Molecular Formula: DN O3
• Molecular Weight: 64.0049
• European Community (EC) Number: 237-024-8
• DSSTox Substance ID: DTXSID80929164
• Wikidata: Q82904005
• Mol file: 13587-52-5.mol

Synonyms:nitricacid99+atom%D65wt.%*solutioninD2

Chemical Property of NITRIC ACID-D

Chemical Property:

• Refractive Index: n20/D 1.3959
• PSA: 66.05000
• LogP: 0.17550
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 64.001919640
• Heavy Atom Count: 4
• Complexity: 24.8

Purity/Quality:

98%min ^*data from raw suppliers

NitricAcid-d ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: O,C
• Statements: 8-35
• Safety Statements: 23-26-36-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [N+](=O)(O)[O-]
• Isomeric SMILES: [2H]O[N+](=O)[O-]

Technology Process of NITRIC ACID-D

There total 7 articles about NITRIC ACID-D which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

deuteroxyl (13587-54-7) + nitric acid (7697-37-2,78989-43-2) → hydroxyl (3352-57-6) + water (14940-63-7) + nitrate radical (12033-49-7,807306-99-6) + nitric acid-d1 (13587-52-5)

Guidance literature:

In gas; Irradiation (UV/VIS); photolysis in Pyrex vessel, gas flow velocity: 5-10 cms**-1, T: 250-, 350 K, p: 20-500 Torr; Kinetics;

DOI:10.1021/jp002394m

Reference yield:

sulfuric acid-d2 (13813-19-9) + potassium nitrate → nitric acid-d1 (13587-52-5)

Guidance literature:

In water-d2; vac.; according to Jolly, G. S., et al., Chem. Phys. Lett., 1985, 117, 132;

DOI:10.1021/j100155a037

Reference yield:

sodium nitrate (7631-99-4) + sulfuric acid-d2 (13813-19-9) → nitric acid-d1 (13587-52-5)

Guidance literature:

In not given; NaNO3 and sulfuric acid were mixed; vacuum distillation: UV;

DOI:10.1021/jp0346413

upstream raw materials:

deuteroxyl

nitric acid

sulfuric acid-d2

sodium nitrate

Downstream raw materials:

water-d2

nitrate radical

deuteroxyl

Nitrogen dioxide

Refernces

• 1、 McCurdy, Patrick R.,Hess, Wayne P.,Xantheas, Sotiris S.. "Nitric acid-water complexes: Theoretical calculations and comparison to experiment". . p. 7628 - 7635. Retrieved 2002.
• 2、 Giligan,Castleman Jr.. "Direct experimental evidence for reactions between dissolved acid halide and chlorine nitrate". . p. 1028 - 1032. Retrieved 2001.
• 3、 MeCabe, David C.,Brown, Steven S.,Gilles, Mary K.,Talukdar, Ranajit K.,Smith, Ian W. M.,Ravishankara. "Kinetics of the Removal of OH(v = 1) and OD(v = 1) by HNO3 and DNO3 from 253 to 383 K". . p. 7762 - 7769. Retrieved 2003.
• 4、 Smith, Ian W. M.,Williams, Martin D.. "". . . Retrieved 1985.