Hexarhodium hexadecacarbonyl

Base Information

• Chemical Name: Hexarhodium hexadecacarbonyl
• CAS No.: 28407-51-4
• Molecular Formula: C16O16 Rh6
• Molecular Weight: 1065.6
• European Community (EC) Number: 249-009-3
• Wikipedia: Hexadecacarbonylhexarhodium
• Wikidata: Q1092934
• Mol file: 28407-51-4.mol

Synonyms:28407-51-4;Hexarhodium hexadecacarbonyl;HEXADECACARBONYLHEXARHODIUM;Hexarhodium(0) hexadecacarbonyl;Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro;rh6(co)16;hexarhodiumhexadecacarbonyl(0);C16O16Rh6;C16-O16-Rh6;SZQABOJVTZVBHE-UHFFFAOYSA-N;FT-0688491;Q1092934;Hexarhodium(0) hexadecacarbonyl, Rh 57-60 % (approx.);Rhodium, tetra-m3-carbonyldodecacarbonylhexa-,octahedro;Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro-

Chemical Property of Hexarhodium hexadecacarbonyl

Chemical Property:

• Melting Point: 238-242°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -3.32800
• Sensitive.: Air Sensitive
• Solubility.: Very sparingly soluble in chloroform, carbon tetrachloride and d
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 16
• Rotatable Bond Count: 0
• Exact Mass: 1065.3516
• Heavy Atom Count: 38
• Complexity: 10

Purity/Quality:

98%,99%, ^*data from raw suppliers

Hexarhodium hexadecacarbonyl, min. 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Rh].[Rh].[Rh].[Rh].[Rh].[Rh]
• Uses: Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds

Technology Process of Hexarhodium hexadecacarbonyl

There total 38 articles about Hexarhodium hexadecacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

[Rh2(CO)2(C8H12)(OSi(C6H5)3)2] (202066-79-3) + carbon monoxide (201230-82-2) → [Rh6(CO)12(μ3-CO)4] (28407-51-4) + [Rh2(CO)4(OSi(C6H5)3)2]

Guidance literature:

In hexane; (argon); stirring (room temp., 10 min);

DOI:10.1039/a704668e

Reference yield:

rhodium(carbonyl)4 (44797-04-8) → [Rh6(CO)12(μ3-CO)4] (28407-51-4) + HRh(carbonyl)4 (75506-18-2)

Guidance literature:

With sulfuric acid; In tetrahydrofuran; acidification (Rh(CO)4)(1-) in tetrahydrofuran below -40°C under1 atm Ar with sulfuric acid;

DOI:10.1021/ic50215a049

Reference yield:

(C6H4CHO2)Rh(C8H12) (79739-00-7) → [Rh6(CO)12(μ3-CO)4] (28407-51-4)

Guidance literature:

With CO; water; In toluene; bubbling of CO through a non-anhydrous soln.;

DOI:10.1016/S0022-328X(00)86106-9

upstream raw materials:

Wilkinson's catalyst

N,N-dimethyl acetamide

carbon monoxide

hydrogen

Refernces

• 1、 Kolesnichenko,Sharikova,Kurkin,Markova,Slivinskii. "Transformation of rhodium carbonyl complexes in hydroformylation of 1-hexene studied from in situ IR spectroscopic data". . p. 704 - 706. Retrieved 1999.
• 2、 Kiriakidou-Kazemifar, Nitsa K.,Haukka, Matti,Pakkanen, Tapani A.,Tunik, Sergey P.,Nordlander, Ebbe. "Formation of rhodium carbonyl thiolate dimers via elimination of dihydrogen; Crystal and molecular structure of [Rh2(CO)4(μ-SC6H4CH3)2]". . p. 65 - 73. Retrieved 2007/10/03.
• 3、 Liu, Guowei,Volken, Romeo,Garland, Marc. "Unmodified Rhodium-Catalyzed Hydroformylation of Alkenes Using Tetrarhodium Dodecacarbonyl. The Infrared Characterization of 15 Acyl Rhodium Tetracarbonyl Intermediates". . p. 3429 - 3436. Retrieved 2008/10/08.