Phosphinic acid, diphenyl-, phenyl ester

Base Information

• Chemical Name: Phosphinic acid, diphenyl-, phenyl ester
• CAS No.: 1706-96-3
• Molecular Formula: C18H15 O2 P
• Molecular Weight: 294.29
• Hs Code.: 2931900090
• NSC Number: 84360
• UNII: XA9Y392YKA
• DSSTox Substance ID: DTXSID80168894
• Nikkaji Number: J50.255C
• Wikidata: Q83038508
• Mol file: 1706-96-3.mol

Synonyms:diphenylphosphoryloxybenzene;1706-96-3;PHOSPHINIC ACID, DIPHENYL-, PHENYL ESTER;Phenyl diphenyldithiophosphinate;Phenyl diphenylphosphinate;NSC 84360;BRN 2738377;XA9Y392YKA;AI3-15094;NSC-84360;0-16-00-00792 (Beilstein Handbook Reference);iphenylphosphinic acid, phenyl ester;WLN: SPR&R&SR;UNII-XA9Y392YKA;Phenyl diphenylphosphinate #;SCHEMBL331195;C18H15O2P;DTXSID80168894;Phenyl (diphenyldithio)phosphinate;NSC84360;C18-H15-O2-P;Diphenylphosphinic acid, phenyl ester;DIPHENYLPHOSPHINIC ACID PHENYL ESTER;LS-106188

Chemical Property of Phosphinic acid, diphenyl-, phenyl ester

Chemical Property:

• Vapor Pressure: 6.07E-07mmHg at 25°C
• Boiling Point: 422.1°Cat760mmHg
• Flash Point: 222.5°C
• PSA: 36.11000
• Density: 1.21g/cm³
• LogP: 3.99450
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 294.08096671
• Heavy Atom Count: 21
• Complexity: 328

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OP(=O)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Phosphinic acid, diphenyl-, phenyl ester

There total 42 articles about Phosphinic acid, diphenyl-, phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

diphenyl-phosphinic acid (1707-03-5) + phenol (108-95-2,27073-41-2) → phenyl diphenylphosphinate (1706-96-3)

Guidance literature:

With N,N-dimethyl-aniline; 1,1'-carbonyldiimidazole; In acetonitrile; at 20 ℃; for 12h; Reagent/catalyst; Solvent; Inert atmosphere;

Reference yield: 97.0%

Diphenylphosphine oxide (4559-70-0) + phenol (108-95-2,27073-41-2) → phenyl diphenylphosphinate (1706-96-3)

Guidance literature:

With chloroform; 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at 25 ℃; for 3h;

DOI:10.1039/c9cc09407e

Reference yield: 97.0%

diphenylphosphane (829-85-6) + phenol (108-95-2,27073-41-2) → phenyl diphenylphosphinate (1706-96-3)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; caesium carbonate; In acetonitrile; at 20 ℃; for 4h; Electrochemical reaction;

DOI:10.1002/chem.202102262

upstream raw materials:

phenyl diphenylphosphinite

Tetraphenyldiphosphin

2-phenoxyacetic acid

1,3,5-Tri-tert-butylbenzene

Downstream raw materials:

diphenyl{1-[3-(4-chlorophenyl)ureido]butyl}phosphine oxide

{Mn(OP(C₆H₅)2OC₆H₅)2Cl₂}

diphenylphosphinamide

diphenyl-phosphinic acid

Refernces

• 1、 Itzstein, Mark von,Jenkins, Ian D.. "A Novel Phosphorus -> Oxygen Phenyl Migration: Triphenylphosphine Dioxide as a Reaction Intermediate". . p. 164 - 165. Retrieved 1983.
• 2、 Abdukader, Ablimit,Dong, Xiaojuan,Jin, Weiwei,Liu, Chenjiang,Wang, Bin,Wang, Ruige,Xia, Yu,Xue, Fei,Zhang, Yonghong. "Electrochemical Enabled Cascade Phosphorylation of N?H/O?H/S?H Bonds with P?H Compounds: An Efficient Access to P(O)-X Bonds". supporting information. p. 14931 - 14935. Retrieved 2021/10/06.
• 3、 Jiang, Zhiyu,Wang, Tianli,Yu, Xiaojun,Zhang, Hong-Su,Zhang, Song. "Highly Efficient and Convenient Access to Phosphinates via CHCl3-Assisted Direct Phosphorylation between R2P(O)H and ROH by Phosphonium Salt Catalysis". supporting information. . Retrieved 2020/05/25.