Zirconium hydroxide

Base Information

• Chemical Name: Zirconium hydroxide
• CAS No.: 14475-63-9
• Deprecated CAS: 1311-54-2,756456-88-9
• Molecular Formula: H₄O₄Zr
• Molecular Weight: 159.253
• European Community (EC) Number: 238-472-7,235-770-9
• UNII: T5YIC9E1JX
• DSSTox Substance ID: DTXSID5065774
• Nikkaji Number: J134.224J
• Wikipedia: Zirconium tetrahydroxide,Zirconium(IV) hydroxide,Zirconium(IV)_hydroxide,Zirconium hydroxide
• Wikidata: Q2349422
• Mol file: 14475-63-9.mol

Synonyms:zirconium hydroxide

Chemical Property of Zirconium hydroxide

Chemical Property:

• Appearance/Colour: white powder
• Melting Point: 550oC, decomposes
• Boiling Point: 100oC at 760 mmHg
• PSA: 80.92000
• Density: 3.25 g/cm³
• LogP: -0.70720
• Water Solubility.: insoluble H2O and alkalies; soluble mineral acids [MER06] [HAW93]
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 157.915657
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Zirconium(IV) hydroxide 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [OH-].[OH-].[OH-].[OH-].[Zr+4]
• Uses: Zirconium hydroxide is used in glass colorants. The compound also is used to prepare zirconium oxide, sulfate, phosphate, and other salts. In the pigment, dye, and glass industries.
• Physical properties: White, bulky amorphous powder; density 3.25 g/cm3; decomposes to oxide at about 500°C; very slightly soluble in water, about 200 mg/L at 20°C; soluble in mineral acids.

Technology Process of Zirconium hydroxide

There total 86 articles about Zirconium hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

water (7732-18-5) + zirconium(IV) chloride (10026-11-6) → zirconium tetrahydroxide (756456-88-9,14475-63-9)

Guidance literature:

With ammonia; at 20 ℃; for 24h; pH=11;

DOI:10.1039/c9ra03406d

Reference yield:

water (7732-18-5) + zirconium(IV) bromide (13777-25-8) → hydrogen bromide (10035-10-6,12258-64-9) + zirconium tetrahydroxide (756456-88-9,14475-63-9)

Guidance literature:

In potassium hydroxide;

Reference yield:

water (7732-18-5) + zirconium(IV) chloride (10026-11-6) → hydrogenchloride (7647-01-0,15364-23-5) + zirconium tetrahydroxide (756456-88-9,14475-63-9)

Guidance literature:

In potassium hydroxide;

upstream raw materials:

zirconyl nitrate

water

zirconyl chloride

zirconyl sulfate

Downstream raw materials:

zirconium fluoride * 3 H2O

zirconium(IV) fluoride

water

zirconium(IV) oxide

Refernces

• 1、 Shmachkova,Kotsarenko,Paukshtis. "On the effect of the strength of acid sites in heterogeneous catalysts on the activity in the skeletal isomerization of n-butane". . p. 554 - 557. Retrieved 2004.
• 2、 Schuster, G.,Braun, G.,Henkel, K.,Querner, G.. "Thermoanalytical investigations on hydrous zirconia". . p. 471 - 478. Retrieved 1988.
• 3、 Liu, Naiwang,Guo, Xiaofeng,Navrotsky, Alexandra,Shi, Li,Wu, Di. "Thermodynamic complexity of sulfated zirconia catalysts". . p. 158 - 163. Retrieved 2016.
• 4、 Il’ichev,Fattakhova,Shashkin,Matyshak,Korchak. "CO oxidation by oxygen of the catalyst and by gas-phase oxygen(0.5–15)%CoO/ZrO2". . p. 300 - 310. Retrieved 2017.
• 5、 Reddy, Benjaram M.,Sreekanth, Pavani M.,Reddy, Vangala R.. "Modified zirconia solid acid catalysts for organic synthesis and transformations". . p. 71 - 78. Retrieved 2005.
• 6、 Thimmaraju,Mohamed Shamshuddin,Pratap,Raja. "Efficient microwave synthesis of novel aromatic esters catalyzed by zirconia and its modified forms: A kinetic study". . p. 99517 - 99528. Retrieved 2015.
• 7、 Yadav, Ganapati D.,Murkute, Ambareesh D.. "Development of a novel mesoporous catalyst UDCaT-6: Kinetics of synthesis of tert-amyl methyl ether (TAME) from tert-amyl alcohol and methanol". . p. 9557 - 9566. Retrieved 2004.
• 8、 Hernández Enríquez,Cortez Lajas,García Alamilla,Castillo Mares,Sandoval Robles,García Serrano. "Synthesis and characterization of mesoporous and nano-crystalline phosphate zirconium oxides". . p. 425 - 428. Retrieved 2009.
• 9、 Cui, Chenwei,Pu, Yongping. "Improvement of energy storage density with trace amounts of ZrO2 additives fabricated by wet-chemical method". . p. 495 - 504. Retrieved 2018.
• 10、 Jong, Rack Sohn,Jun, Seob Lim,Si, Hoon Lee. "A new solid superacid catalyst prepared by doping ZrO2 with Ce and modifying with sulfate simultaneously". . p. 1490 - 1491. Retrieved 2004.