Aldicarb sulfoxide

Base Information

• Chemical Name: Aldicarb sulfoxide
• CAS No.: 1646-87-3
• Molecular Formula: C7H14 N2 O3 S
• Molecular Weight: 206.266
• Hs Code.: 2930909090
• European Community (EC) Number: 622-554-8
• UNII: 5X736K018B
• Wikidata: Q27269178
• ChEMBL ID: CHEMBL1533560
• Mol file: 1646-87-3.mol

Synonyms:aldicarb sulfoxide;propionaldehyde, 2-methyl-2-(methylsulfinyl)-, O-(methylcarbamoyl)oxime;Temik sulfoxide

Chemical Property of Aldicarb sulfoxide

Chemical Property:

• Melting Point: 108-110 °C
• Refractive Index: 1.5690 (estimate)
• Boiling Point: °Cat760mmHg
• PKA: 13.57±0.46(Predicted)
• Flash Point: °C
• PSA: 86.97000
• Density: 1.21g/cm³
• LogP: 1.74190
• Storage Temp.: 2-8°C
• XLogP3: -0.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 206.07251349
• Heavy Atom Count: 13
• Complexity: 238

Purity/Quality:

98%Min ^*data from raw suppliers

AldicarbSulfoxide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+,N
• Statements: 28-50
• Safety Statements: 22-24/25-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)(C=NOC(=O)NC)S(=O)C
• Isomeric SMILES: CC(C)(/C=N/OC(=O)NC)S(=O)C
• Uses: Aldicarb Sulfoxide is an analog of Aldicarb (A514650) detected in agricultural products as pesticide residue.

Technology Process of Aldicarb sulfoxide

There total 2 articles about Aldicarb sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

temik (116-06-3) → aldicarb sulfoxide (1646-87-3)

Guidance literature:

With peracetic acid; molybdenyl acetonylacetonate; In benzene; at 20 ℃; for 24h;

Reference yield:

→ aldicarb sulfoxide (1646-87-3)

Guidance literature:

Carbamyloxim XII, Peressigsaeure;

DOI:10.1021/jf60146a007

Reference yield:

aldicarb sulfoxide (1646-87-3) → methylamine (74-89-5)

Guidance literature:

aluminium; In water; acetonitrile; Product distribution; Irradiation; influence of aluminum foil;;

DOI:10.1021/ac00154a007

upstream raw materials:

temik

Downstream raw materials:

methylamine

Refernces

• 1、 Rouchard, Jean,Moons, Chantal,Meyer, Joseph. "Catalyse de l'oxydation par l'acid peracetique de sulfures organiques, contenant des fonctions fragiles, en sulfoxydes et sulfones correspondants". . p. 441 - 443. Retrieved 2007/10/02.