Ethyl vinyl sulfone

Base Information

• Chemical Name: Ethyl vinyl sulfone
• CAS No.: 1889-59-4
• Molecular Formula: C4H8O2S
• Molecular Weight: 120.172
• Hs Code.: 2904100000
• European Community (EC) Number: 217-567-7
• NSC Number: 186282
• UNII: 6KM6G9NMM2
• DSSTox Substance ID: DTXSID90172260
• Nikkaji Number: J199.712B
• Wikidata: Q2118652
• Mol file: 1889-59-4.mol

Synonyms:ethyl vinyl sulfone

Chemical Property of Ethyl vinyl sulfone

Chemical Property:

• Appearance/Colour: clear yellow liquid
• Vapor Pressure: 0.0705mmHg at 25°C
• Refractive Index: n20/D 1.463(lit.)
• Boiling Point: 237 °C at 760 mmHg
• Flash Point: 109 °C
• PSA: 42.52000
• Density: 1.085 g/cm³
• LogP: 1.64540
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 120.02450067
• Heavy Atom Count: 7
• Complexity: 138

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ethyl vinyl sulfone ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCS(=O)(=O)C=C

Technology Process of Ethyl vinyl sulfone

There total 11 articles about Ethyl vinyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

vinyl ethylsulfide (627-50-9) → ethyl vinyl sulfone (1889-59-4)

Guidance literature:

With urea hydrogen peroxide adduct; In ethanol; at 20 ℃; for 0.25h;

DOI:10.1016/j.catcom.2020.105931

Reference yield: 30.0%

methyl ethylsulfonyl(diazo)acetate → ethyl vinyl sulfone (1889-59-4)

Guidance literature:

at 600 ℃; for 2.77778E-06h; under 0.01 Torr;

DOI:10.1039/c39940000805

Reference yield:

1-bromo-2-ethanesulfonyl-ethane (30129-83-0) → ethyl vinyl sulfone (1889-59-4)

Guidance literature:

With potassium hydroxide; at 25 ℃;

upstream raw materials:

2-chloroethyl ethyl sulfone

1-bromo-2-ethanesulfonyl-ethane

2-ethanesulfonylethanol

triethylamine

Downstream raw materials:

2-ethanesulfonylethanol

1,2-dibromo-1-ethanesulfonyl-ethane

disulfoton sulphone

1-ethanesulfonyl-2-benzylsulfanyl-ethane

Refernces

• 1、 Tilley, R. Ian,Leslie, D. Ralph. "Rates of Reaction of the Sulfoxides and Sulfones of Sulfur Mustard and 2-Chloroethyl Ethyl Sulfide with Hydroxide Ion in Water". . p. 1781 - 1786. Retrieved 1995.
• 2、 Bianchi, Pauline,Emmanuel, Noémie,Legros, Julien,Monbaliu, Jean-Christophe M.. "A safe and compact flow platform for the neutralization of a mustard gas simulant with air and light". supporting information. p. 4105 - 4115. Retrieved 2020/07/30.
• 3、 Aitken, R. Alan,Armstrong, Jill M.,Drysdale, Martin J.,Ross, Fiona C.,Ryan, Bruce M.. "Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 15. Generation of alkoxycarbonyl(sulfenyl)carbenes and their intramolecular insertion to give alkenyl sulfides". . p. 593 - 604. Retrieved 2007/10/03.