Tri(N,N-di-n-propylamino)phosphine

Base Information

• Chemical Name: Tri(N,N-di-n-propylamino)phosphine
• CAS No.: 5848-64-6
• Molecular Formula: C18H42 N3 P
• Molecular Weight: 331.525
• European Community (EC) Number: 666-863-6
• DSSTox Substance ID: DTXSID60207174
• Nikkaji Number: J1.100.519E
• Wikidata: Q83081070
• Mol file: 5848-64-6.mol

Synonyms:5848-64-6;Tri(N,N-di-n-propylamino)phosphine;Hexa-n-propyl phosphorous triamide;HEXA-N-PROPYLPHOSPHOROUSTRIAMIDE;N-bis(dipropylamino)phosphanyl-N-propylpropan-1-amine;Tris(dipropylamino)phosphine;Tris(N,N-di-n-propylamino)phosphine;SCHEMBL8596560;Phosphine, tris(dipropylamino)-;DTXSID60207174;KPDXRSBWIPGWLS-UHFFFAOYSA-N;P(N(n-C3H7)2)3;FT-0627041;N,N,N',N',N'',N''-hexapropylphosphinetriamine

Chemical Property of Tri(N,N-di-n-propylamino)phosphine

Chemical Property:

• Vapor Pressure: 6.15E-06mmHg at 25°C
• Boiling Point: 378.8°Cat760mmHg
• PKA: 12.51±0.70(Predicted)
• Flash Point: 182.9°C
• PSA: 23.31000
• Density: g/cm³
• LogP: 5.57930
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 15
• Exact Mass: 331.31163535
• Heavy Atom Count: 22
• Complexity: 182

Purity/Quality:

98%Min ^*data from raw suppliers

HEXAISOPROPYL PHOSPHORUS TRIAMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: R36/38:Irritating to eyes and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36:Wear suitable prot

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCN(CCC)P(N(CCC)CCC)N(CCC)CCC

Technology Process of Tri(N,N-di-n-propylamino)phosphine

There total 6 articles about Tri(N,N-di-n-propylamino)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

C24H56N4P(1+)*I(1-) (81175-44-2) → Tris(di-n-propylamino)phosphine (5848-64-6)

Guidance literature:

With ammonia; sodium; at -30 ℃; for 8h;

Reference yield: 60.0%

di-n-propylamine (142-84-7) → Tris(di-n-propylamino)phosphine (5848-64-6)

Guidance literature:

With phosphorus trichloride; In hexane; at 20 ℃; for 2h;

DOI:10.1515/znb-1999-0121

Reference yield: 13.0%

tetrakis(dipropylamino)phosphonium bromide → Tris(di-n-propylamino)phosphine (5848-64-6) + hexapropylphosphoric triamide (13987-57-0) + hydrochloride of heptapropylphosphorimidic triamide

Guidance literature:

With sodium hydroxide; at 200 ℃; under 0.02 Torr; Product distribution; Mechanism;

upstream raw materials:

dipropyl-amidophosphoric acid-dichloride

di-n-propylamine

C₂₄H₅₆N₄P⁽¹⁺⁾*I^(1-)

Downstream raw materials:

C₂₄H₄₇N₃PSe⁽¹⁺⁾*I^(1-)

2-Dipropylamino-1,3-diphenyl-[1,3,2]diazaphosphetidin-4-one

(2-Phenyl-2H-8-thia-1,2,3a-triaza-3-phospha-cyclopenta[a]inden-3-yl)-dipropyl-amine

N-phenyl-N',N'-di(n-propyl)urea

Refernces

• 1、 Marchenko, A. P.,Koidan, G. N.,Pinchuk, A. M.. "REACTIONS OF TETRAKIS(DIALKYLAMINO)PHOSPHONIUM BROMIDES WITH BASES". . p. 2405 - 2409. Retrieved 2007/10/02.