Cyclodecane

Base Information

• Chemical Name: Cyclodecane
• CAS No.: 293-96-9
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• European Community (EC) Number: 206-032-3
• UNII: 9N3JJ4GTR5
• DSSTox Substance ID: DTXSID7059779
• Nikkaji Number: J193.701D
• Wikipedia: Cyclodecane
• Wikidata: Q118815
• Mol file: 293-96-9.mol

Synonyms:CYCLODECANE;293-96-9;EINECS 206-032-3;9N3JJ4GTR5;cyclodecan;Cyclodecane, >=90%;UNII-9N3JJ4GTR5;DTXSID7059779;MFCD00003711;AKOS015915993;FT-0624160;D89414;A820228;Q118815;J-017495

Chemical Property of Cyclodecane

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 0.447mmHg at 25°C
• Melting Point: 9-10 °C(lit.)
• Refractive Index: n20/D 1.471(lit.)
• Boiling Point: 200.999 °C at 760 mmHg
• Flash Point: 58.781 °C
• PSA: 0.00000
• Density: 0.791 g/cm³
• LogP: 3.90100
• Water Solubility.: 0.33mg/L(25 oC)
• XLogP3: 5.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 140.156500638
• Heavy Atom Count: 10
• Complexity: 33.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cyclodecane >94.0%(GC) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCCCCCCC1

Technology Process of Cyclodecane

There total 14 articles about Cyclodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.5%

Cyclohexanone diperoxide (183-84-6) → hexahydro-2H-oxepin-2-one (502-44-3,24980-41-4,80137-66-2) + oxacyclododecan-2-one (1725-03-7) + cyclodecane (293-96-9)

Guidance literature:

With toluene-4-sulfonic acid; In 2,2,2-trifluoroethanol; at 25 ℃; for 0.666667h; Reagent/catalyst; Solvent; Temperature;

Reference yield:

cyclododecane (294-62-2) → 1-hexene (592-41-6,25067-06-5) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + 1-dodecene (112-41-4,25067-08-7,62132-67-6) + ethene (74-85-1) + nona-1,8-diene (4900-30-5) + cyclodecane (293-96-9)

Guidance literature:

With water; at 670 - 770 ℃; Thermodynamic data; Kinetics; Product distribution; further objects of study: mechanism, activation energy, frequency factor, dependence of ethylene yield distribution from temperature;

Reference yield:

trans-tricyclo<7.1.0.04,6>deca-2,7-diene → cyclodecane (293-96-9) + bicyclo<7.1.0>decane (286-76-0,66537-41-5) + trans-tricyclo<7.1.0.04,6>decane (286-73-7,89955-58-8,89955-59-9)

Guidance literature:

With hydrogen; nickel; In hexane; at 60 ℃; for 1h; under 60800 Torr; Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00952847

upstream raw materials:

6-hydroxycyclodecan-1-one

2-hydroxycyclodecanone

cyclodecyne

(+/-)-6-methoxycyclodecanone

Downstream raw materials:

1,10-decanedioic acid

azulene

propene

methane

Refernces

• 1、 Story et al.. "". . p. 817. Retrieved 1968.
• 2、 Liu, Fuchen,Goldman, Alan S.. "Efficient thermochemical alkane dehydrogenation and isomerization catalyzed by an iridium pincer complex". . p. 655 - 656. Retrieved 2007/10/03.
• 3、 Tomilov, Yu. V.,Mitenina, T. L.,Lutsenko, A. I.,Dolgii, I. E.,Kolesnikov, S. P.,Nefedov, O. M.. "REACTION OF UNSATURATED COMPOUNDS WITH DIAZOLAKANES. COMMUNICATION 3. CYCLOPROPANATION OF OF CYCLOOCTATETRAENE WITH DIAZOMETHANE". . p. 65 - 72. Retrieved 2007/10/02.