Trisodium;phosphanide

Base Information

• Chemical Name: Trisodium;phosphanide
• CAS No.: 12058-85-4
• Molecular Formula: Na₃P
• Molecular Weight: 99.9431
• DSSTox Substance ID: DTXSID401313844
• Mol file: 12058-85-4.mol

Synonyms:Na3P;DTXSID401313844

Chemical Property of Trisodium;phosphanide

Chemical Property:

• Melting Point: stable up to 650℃ [KIR82]
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 0.05810
• Water Solubility.: decomposes in H2O, evolving PH3 [CRC10] [HAW93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 101.95871991
• Heavy Atom Count: 4
• Complexity: 3.2

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): Dangerous fire risk, reacts with water and acids to form phosphine.
• Hazard Codes: Dangerous fire risk, reacts with water and acids to form phosphine.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Na+].[Na+].[Na+].[PH2-]

Technology Process of Trisodium;phosphanide

There total 19 articles about Trisodium;phosphanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

phosphorus + sodium (7440-23-5) → sodium phosphide (12058-85-4)

Guidance literature:

With naphthalene; In tetrahydrofuran; at 50 ℃; for 12.5h;

Reference yield:

phosphorus pentachloride (10026-13-8,874483-75-7) + sodium (7440-23-5) → sodium phosphide (12058-85-4) + sodium chloride (7647-14-5)

Guidance literature:

In neat (no solvent); explosive reaction of molten Na with PCl5;;

Reference yield:

phosphorus + sodium (7440-23-5) → sodium phosphide (12058-85-4)

Guidance literature:

With naphthalene; In 1,2-dimethoxyethane; at 75 ℃; for 20h;

upstream raw materials:

sodium

phosphorus trichloride

phosphorus pentachloride

phosphan

Downstream raw materials:

gallium phosphide

iron monophosphide

zirconium phosphide

hafnium phosphide

Refernces

• 1、 Peterson,Logan. "". . p. 53,57. Retrieved 1966.
• 2、 Yunle, Gu,Fan, Guo,Yitai, Qian,Huagui, Zheng,Ziping, Yang. "A solvothermal synthesis of ultra-fine iron phosphide". . p. 1101 - 1105. Retrieved 2002.
• 3、 Weinberger, Gernot P.,Sommer, Florian,Torvisco, Ana,Fischer, Roland C.,Flock, Michaela. "Exploration of Novel α,ω-Substituted Diphosphatrisilanes by Combining Experimental Methods and DFT Calculations". . p. 3778 - 3785. Retrieved 2020.
• 4、 Sietzen, Malte,Batke, Sonja,Merz, Lukas,Wadepohl, Hubert,Ballmann, Joachim. "Phospha derivatives of Tris(2-aminoethyl)amine (tren) and tris(3-aminopropyl)amine (trpn): Synthesis and complexation studies with group 4 metals". . p. 1118 - 1128. Retrieved 2015.