Chlorophenylsilane

Base Information

• Chemical Name: Chlorophenylsilane
• CAS No.: 4206-75-1
• Molecular Formula: C6H7 Cl Si
• Molecular Weight: 142.66
• Hs Code.: 2931900090
• European Community (EC) Number: 224-124-1
• DSSTox Substance ID: DTXSID70871062
• Mol file: 4206-75-1.mol

Synonyms:Chlorophenylsilane;4206-75-1;Phenylchlorosilane;chloro(phenyl)silicon;Silane, chlorophenyl-;Benzene, (chlorosilyl)-;chloro(phenyl)silane;EINECS 224-124-1;C6H7ClSi;Chlorophenylsilane 97;Silane, chlorophenyl-,;C6-H7-Cl-Si;SCHEMBL167123;SCHEMBL167124;DTXSID70871062;AKOS015915842

Chemical Property of Chlorophenylsilane

Chemical Property:

• Vapor Pressure: 2.45mmHg at 25°C
• Refractive Index: n20/D 1.5260(lit.)
• Boiling Point: 165.5°Cat760mmHg
• Flash Point: 53.9°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.63450
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 139.9849044
• Heavy Atom Count: 8
• Complexity: 59.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chlorophenylsilane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 10-34
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Si]Cl

Technology Process of Chlorophenylsilane

There total 15 articles about Chlorophenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

phenylsilane (694-53-1) → phenylchlorosilane (4206-75-1)

Guidance literature:

With dichloromethane; eosin y; at 30 ℃; Flow reactor; Inert atmosphere; Irradiation; Green chemistry;

DOI:10.1002/anie.201908556

Reference yield: 86.0%

phenylsilane (694-53-1) → dichlorophenylsilane (1631-84-1) + phenylchlorosilane (4206-75-1)

Guidance literature:

With hydrogenchloride; In diethylene glycol dimethyl ether; at 60 ℃; for 60.5h; Temperature; Solvent;

Reference yield: 38.0%

Phenyltrichlorosilane (98-13-5) → dichlorophenylsilane (1631-84-1) + phenylsilane (694-53-1) + phenylchlorosilane (4206-75-1)

Guidance literature:

With sodium hydride; lithium chloride; In diethylene glycol dimethyl ether; at 160 ℃; for 14h; Inert atmosphere;

upstream raw materials:

diphenylsilane

phenylsilane

Phenyltrichlorosilane

1,1,1,3-tetrachloropropane

Downstream raw materials:

tris(dimethylsilyl)(phenylsilyl)hydrazine

1,3-diphenyl-disiloxane

1,3-diphenyldisilthiane

tris(phenylsilyl)hydrazine

Refernces

• 1、 Chen, Yi,Li, Yongming,Xu, Caihong. "Facile preparation of hydrochlorosilane by alkali metal halide catalyzed Si-H/Si-Cl redistribution reaction". supporting information. . Retrieved 2020/09/21.
• 2、 -. "SYNTHESIS OF ORGANO CHLOROSILANES FROM ORGANOSILANES". Page/Page column 36; 37; 38; 39; 40; 46. . Retrieved 2019/04/16.