2-Bromoethyl(diethyl)azanium;bromide

Base Information

• Chemical Name: 2-Bromoethyl(diethyl)azanium;bromide
• CAS No.: 1069-72-3
• Molecular Formula: C6H14 Br N . Br H
• Molecular Weight: 261
• Hs Code.: 2921199090
• Mol file: 1069-72-3.mol

Synonyms:2-bromoethyl(diethyl)azanium;bromide;2-Bromo-N,N-diethylethan-1-aminium bromide;NS00042367

Chemical Property of 2-Bromoethyl(diethyl)azanium;bromide

Chemical Property:

• Vapor Pressure: 2.25mmHg at 25°C
• Melting Point: 211-215?°C (dec.)(lit.)
• Boiling Point: 161.6°C at 760 mmHg
• Flash Point: 51.5°C
• PSA: 3.24000
• Density: 1.216g/cm³
• LogP: 2.68120
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 260.95508
• Heavy Atom Count: 9
• Complexity: 43.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Bromo-N,N-diethylethylamine hydrobromide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 25-37/38-41
• Safety Statements: 26-39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[NH+](CC)CCBr.[Br-]

Technology Process of 2-Bromoethyl(diethyl)azanium;bromide

There total 1 articles about 2-Bromoethyl(diethyl)azanium;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2-(Diethylamino)ethanol (100-37-8) → 2-bromo-N,N-diethylethanamine hydrobromide (1069-72-3)

Guidance literature:

With hydrogen bromide; phosphorus tribromide; at 140 ℃; for 11h;

Reference yield: 98.0%

2-bromo-N,N-diethylethanamine hydrobromide (1069-72-3) + N-(2,4,6-trimethylphenyl)imidazole (25364-44-7) → 1-[2-(diethylamino)ethyl]-3-mesitylimidazolium bromide hydrobromide

Guidance literature:

In acetonitrile; at 80 - 150 ℃; for 48h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.ejmech.2014.07.086

Reference yield: 93.0%

methyl N-(4-[4-(benzyloxy)-2-oxopyridin-1(2H)-yl]-phenyl)carbamate (1266775-09-0) + 2-bromo-N,N-diethylethanamine hydrobromide (1069-72-3) → methyl N-(4-[4-(benzyloxy)-2-oxopyridin-1(2H)-yl]-phenyl)-N-[2-(diethylamino)ethyl]carbamate (1266775-40-9)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 1.5h;

DOI:10.1016/j.bmc.2010.12.002

upstream raw materials:

2-(Diethylamino)ethanol

Downstream raw materials:

1-[2-(2-diethylamino-ethoxy)-4-methoxy-phenyl]-ethanone

4-(2-diethylamino-ethylamino)-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-one

1,5,1',5'-tetramethyl-2,2'-diphenyl-1,2,1',2'-tetrahydro-4,4'-ethanediyldiamino-bis-pyrazol-3-one

diethyl-[2-(4-phenoxy-phenoxy)-ethyl]-amine

Refernces