Magnesium, (phthalocyaninato(2-))-

Base Information

• Chemical Name: Magnesium, (phthalocyaninato(2-))-
• CAS No.: 1661-03-6
• Deprecated CAS: 1015854-23-5
• Molecular Formula: C32H16 Mg N8
• Molecular Weight: 536.838
• European Community (EC) Number: 216-766-6
• DSSTox Substance ID: DTXSID80937168
• Wikidata: Q27122476
• Mol file: 1661-03-6.mol

Synonyms:EINECS 216-766-6;MAGNESIUM, (PHTHALOCYANINATO(2-))-;(29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32)magnesium;Magnesium, [phthalocyaninato(2-)]-;Magnesium, (29H,31H-phthalocyaninato(2-)-N29,N39,N31,N32)-, (SP-4-1)-;[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]magnesium;MAGNESIUMPHTHALOCYANINE;Phthalocyanine Magnesium(II);DTXSID80937168;NIQREIWCURIAMA-UHFFFAOYSA-N;Magnesium phthalocyanine-6,30-diide;LS-88602;P1018;J-010257;Q27122476

Chemical Property of Magnesium, (phthalocyaninato(2-))-

Chemical Property:

• Appearance/Colour: green powder.
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 84.02000
• Density: g/cm³
• LogP: 1.46440
• Solubility.: Soluble in concentrated sulfuric acid.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 536.1348342
• Heavy Atom Count: 41
• Complexity: 709

Purity/Quality:

98%,99%, ^*data from raw suppliers

Magnesium(II) Phthalocyanine ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=C5C=CC=CC5=C([N-]4)N=C6C7=CC=CC=C7C(=N6)N=C8C9=CC=CC=C9C(=N8)N=C2[N-]3.[Mg+2]
• Uses: Magnesium phthalocyanine is used in preparing membrane sensors for cyanide ions. Also used in preparation of membrane sensors for cyanide ions.

Technology Process of Magnesium, (phthalocyaninato(2-))-

There total 12 articles about Magnesium, (phthalocyaninato(2-))- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

phthalonitrile (91-15-6) → magnesium phthalocyanine (1661-03-6)

Guidance literature:

With magnesium chloride; for 0.0833333h; microwave irradiation;

DOI:10.3390/61000831

Reference yield: 39.0%

magnesium acetate (142-72-3,92123-19-8) + phthalonitrile (91-15-6) → magnesium(II) phthalocyanine (1661-03-6)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; at 200 ℃; High pressure;

DOI:10.1016/j.molstruc.2021.131422

Reference yield: 27.0%

phthalonitrile (91-15-6) → magnesium(II) phthalocyanine (1661-03-6)

Guidance literature:

With magnesium; In neat (no solvent);

DOI:10.1016/j.molstruc.2021.131422

upstream raw materials:

phthalonitrile

1,4,7,10-tetraoxa-13,16-dithiacyclooctadec-14-en-14,15-dicarbonitrile

5,7-diphenyl-6H-1,4-diazepine-2,3-dicarbonitrile

5,6-diphenyl-pyrazine-2,3-dicarbonitrile

Downstream raw materials:

29H,31H-Phthalocyanine

Refernces

• 1、 Wieczorek, Ewelina,Mlynarczyk, Dariusz T.,Kucinska, Malgorzata,Dlugaszewska, Jolanta,Piskorz, Jaroslaw,Popenda, Lukasz,Szczolko, Wojciech,Jurga, Stefan,Murias, Marek,Mielcarek, Jadwiga,Goslinski, Tomasz. "Photophysical properties and photocytotoxicity of free and liposome-entrapped diazepinoporphyrazines on LNCaP cells under normoxic and hypoxic conditions". . p. 64 - 73. Retrieved 2018.
• 2、 Tanno,Woehrle,Kaneko,Yamada. "RAPID PHOTOREDUCTION OF METHYL VIOLOGEN WITH VISIBLE LIGHT USING METAL-PHTHALOCYANINES AS SENSITIZERS.". . p. 1032 - 1034. Retrieved 1980.
• 3、 Liu, Limin,Zhang, Xian-Fu. "Group IIA alkaline-earth metal phthalocyanines: Synthesis, photoluminescence and singlet oxygen formation". . . Retrieved 2021/09/14.