1,2-Epoxy-7-octene

Base Information

• Chemical Name: 1,2-Epoxy-7-octene
• CAS No.: 19600-63-6
• Molecular Formula: C₈H₁₄O
• Molecular Weight: 126.199
• Hs Code.: 29109000
• European Community (EC) Number: 243-178-7
• DSSTox Substance ID: DTXSID30941376
• Nikkaji Number: J225.233C
• Wikidata: Q82918192
• Mol file: 19600-63-6.mol

Synonyms:1,2-Epoxy-7-octene;19600-63-6;2-hex-5-enyloxirane;Oxirane, 5-hexenyl-;5-Hexenyloxirane;7,8-Epoxyoctene;CCRIS 3749;EINECS 243-178-7;BRN 1305290;2-(hex-5-en-1-yl)oxirane;5-17-01-00231 (Beilstein Handbook Reference);(2R)-2-hex-5-enyloxirane;2-hex-5-en-yloxirane;2-(5-Hexenyl)oxirane;2-(hex-5-enyl)oxirane;1,7-octadiene monoepoxide;2-(5-Hexenyl)oxirane #;1-Octene, 7,8-epoxy-;SCHEMBL132825;7,8-EPOXY-1-OCTENE;Oxirane,2-(5-hexen-1-yl)-;DTXSID30941376;MFCD00005156;AKOS025294826;LS-101050;FT-0606442;FT-0606443;EN300-7613273;A813830;J-640006;J-800006;Z1255356056

Chemical Property of 1,2-Epoxy-7-octene

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 3.96mmHg at 25°C
• Refractive Index: 1.4345-1.4365
• Boiling Point: 155.1°Cat760mmHg
• Flash Point: 38.3°C
• PSA: 12.53000
• Density: 0.882g/cm³
• LogP: 2.13160
• Storage Temp.: 0-6°C
• Water Solubility.: Not miscible in water.
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 126.104465066
• Heavy Atom Count: 9
• Complexity: 88.6

Purity/Quality:

99% ^*data from raw suppliers

1,2-Epoxy-7-octene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 41-37/38-19-10-36/37/38
• Safety Statements: 37/39-26-18-36/37/39-16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCCC1CO1
• Uses: 1,2-Epoxy-7-octene is used as an organic chemical synthesis intermediate.

Technology Process of 1,2-Epoxy-7-octene

There total 5 articles about 1,2-Epoxy-7-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-(4-Oxiranyl-butyl)-thiiran (16573-03-8) → 1,2-epoxy-7-octene (52485-73-1,105205-70-7,126872-17-1,19600-63-6)

Guidance literature:

With hydrogen sulfide; triphenylphosphine; methyltrioxorhenium(VII); In [D₃]acetonitrile; for 2h; Ambient temperature;

DOI:10.1039/a901708i

Reference yield: 90.0%

1,7-Octadiene (3710-30-3) → 1,2-epoxy-7-octene (52485-73-1,105205-70-7,126872-17-1,19600-63-6)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 2h; Inert atmosphere;

DOI:10.1021/jo4014996

Reference yield:

1,7-Octadiene (3710-30-3) → 1,2,7,8-diepoxyoctane (2426-07-5) + 1,2-epoxy-7-octene (52485-73-1,105205-70-7,126872-17-1,19600-63-6)

Guidance literature:

With oxygen; isobutyraldehyde; silica-supported cobalt acetate; In dichloromethane; at 19 ℃; for 24h;

DOI:10.1039/cc9960001859

upstream raw materials:

1,7-Octadiene

2-(4-Oxiranyl-butyl)-thiiran

Downstream raw materials:

octanol

1,2-Epoxyoctane

1-(2-nitrophenoxy)oct-7-en-2-ol

5-fluoro-2-nitro-1-{[1-(2-nitrophenoxymethyl)oct-7-en-2-yl]oxy}benzene

Refernces

• 1、 Toda, Hiroshi,Imae, Ryouta,Itoh, Nobuya. "Bioproduction of chiral epoxyalkanes using styrene monooxygenase from rhodococcus sp. ST-10 (RhSMO)". . p. 3443 - 3450. Retrieved 2015/02/05.
• 2、 Kadyrov, Renat. "Low catalyst loading in ring-closing metathesis reactions". supporting information. p. 1002 - 1012. Retrieved 2013/02/23.