Phenyltrichlorogermane

Base Information

• Chemical Name: Phenyltrichlorogermane
• CAS No.: 1074-29-9
• Molecular Formula: C6H5 Cl3 Ge
• Molecular Weight: 256.055
• Hs Code.: 2931900090
• European Community (EC) Number: 214-039-8
• NSC Number: 269585
• DSSTox Substance ID: DTXSID80148035
• Nikkaji Number: J208.904A
• Wikidata: Q29563671
• Mol file: 1074-29-9.mol

Synonyms:Phenyltrichlorogermane;1074-29-9;Phenylgermanium trichloride;Trichloro(phenyl)germane;Trichlorophenylgermane;Germanium phenyl trichloride;EINECS 214-039-8;Phenylgermanium trichloride, 98%;NSC269585;C6H5Cl3Ge;Phenylgermaniumtrichloride;Germane, trichlorophenyl-;Trichloro(phenyl)germane #;C6-H5-Cl3-Ge;SCHEMBL123030;[Ge](Cl)(Cl)(Cl)c1ccccc1;DTXSID80148035;BAA07429;MFCD00000460;AKOS015840466;NSC 269585;NSC-269585;CS-0440754;P1003;T71578

Chemical Property of Phenyltrichlorogermane

Chemical Property:

• Vapor Pressure: 0.0882mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: n20/D 1.554(lit.)
• Boiling Point: 232.8°Cat760mmHg
• Flash Point: 92.2°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.17450
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 255.866861
• Heavy Atom Count: 10
• Complexity: 104

Purity/Quality:

98%,99%, ^*data from raw suppliers

Phenylgermanium Trichloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 20/21/22-34
• Safety Statements: 26-27-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Ge](Cl)(Cl)Cl

Technology Process of Phenyltrichlorogermane

There total 70 articles about Phenyltrichlorogermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.8%

germaniumtetrachloride (10038-98-9) + dichloromethylphenylsilane (149-74-6) → trichlorophenylgermane (1074-29-9)

Guidance literature:

With AlCl₃; In neat (no solvent); byproducts: CH3SiCl3; heated at 100°C for 2 h with removal of CH3SiCl3 (reflux ratio 15); heated at 100°C for 6 h and then at 120°C; AlCl3 filtered off; filtrate distd.; elem. anal.;

Reference yield: 90.0%

germaniumtetrachloride (10038-98-9) + diphenylsilyl dichloride (80-10-4) → trichlorophenylgermane (1074-29-9)

Guidance literature:

aluminium trichloride; In not given; Si-compound reacted with GeCl4 in presence of AlCl3 at 110-120°C for 3 h;

DOI:10.1134/S1070363206100100

Reference yield: 80.0%

phenylgermane (2875-92-5) + copper dichloride → trichlorophenylgermane (1074-29-9)

Guidance literature:

copper(l) iodide; In toluene; hydrogermane mixed with 6 equiv. of CuCl2 and CuI in toluene under reflux for 17 days; solvent evapd., distilled under reduced pressure;

DOI:10.1246/cl.2001.886

upstream raw materials:

adamantane

Triphenylsilyl chloride

diphenylsilyl dichloride

chloro(methyl)phenylsilane

Downstream raw materials:

(C₆H₅)GeOOH

phenyltriiodogermane

tributyltin chloride

phenylgermane

Refernces

• 1、 Petrosyan, V. A.,Niyazymbetov, M. E.,Kolesnikov, S. P.,Li, V. Ya.. "". . . Retrieved 1987.
• 2、 Ohshita, Joji,Toyoshima, Yutaka,Iwata, Arihiro,Tang, Heqing,Kunai, Atsutaka. "Selective synthesis of chlorohydrogermanes from mono-, di-, and trihydrogermanes". . p. 886 - 887. Retrieved 2001.
• 3、 Myalochkin,Kochina,Avrorin,Vrazhnov,Sinotova. "Gas phase reaction of nucleogenic dimethylgermylium cations with benzene". . p. 1762 - 1766. Retrieved 2011/02/24.