TIN (IV) ISOPROPOXIDE

Base Information

• Chemical Name: TIN (IV) ISOPROPOXIDE
• CAS No.: 1184-61-8
• Molecular Formula: 4C₃H₇O*Sn
• Molecular Weight: 355.062
• Hs Code.: 29051220
• Mol file: 1184-61-8.mol

Synonyms:Isopropylalcohol, tin(4+) salt (8CI);Isopropyl stannate(IV) (6CI,7CI);Alcofine SN 31;Tetraisopropoxystannane;Tetraisopropyl stannate;Tin tetraisopropoxide;Tin(4+) isopropoxide;Tin(IV) isopropoxide;

Chemical Property of TIN (IV) ISOPROPOXIDE

Chemical Property:

• Melting Point: 130°C (dec.)
• Boiling Point: 131°C 1,6mm
• Flash Point: 131°C/1.6mm
• PSA: 36.92000
• Density: 0.8387 g/mL at 25 °C
• LogP: 3.12200
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in hydrocarbons, reacts with alcohols, ketones and ester

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tin(IV)isopropoxide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 20/21/22-67-36-11
• Safety Statements: 23-36/37/39-45-26-16

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Tin(IV) isopropoxide is used as a precursor for the preparation of tin oxide nanoparticles, thin films, indium tin oxide (ITO) films , which shows desired electrochemical and conducting properties. Doped tin oxide nanoparticles and thin films find application as gas sensors.

Technology Process of TIN (IV) ISOPROPOXIDE

There total 2 articles about TIN (IV) ISOPROPOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(bis(trimethylsilyl)amido)tin(II) (55147-78-9) + isopropyl alcohol (67-63-0,8013-70-5) → tin isopropoxide (1184-61-8,35835-86-0,99504-10-6,132951-93-0)

Guidance literature:

In diethyl ether; inert atmosphere; dropwise addn. of excess i-PrOH to Sn-compd.; solvent removal; sublimable (120°C/0.01 Torr);

Reference yield:

→ tin isopropoxide (1184-61-8,35835-86-0,99504-10-6,132951-93-0)

Guidance literature:

Tetrakis-ethoxy-zinn, Propanol-(2); Reindarst. ueber das Propanol-(2)-Solvat 2 C12H28O4Sn*2 C3H8O;

DOI:10.1139/v62-179

Reference yield:

tin isopropoxide (1184-61-8,35835-86-0,99504-10-6,132951-93-0) → tin (7440-31-5)

Guidance literature:

In neat (no solvent); byproducts: i-PrOH, acetone; absence of air and moisture; evacuation to 0.01 Torr, heating sample to 110°C, deposition in hot zone (350°C), collecting org. products at liquid N2-temp.; cooling to 25°C over 4 h; powder X-ray diffraction, NMR spectroscopy of org. products;

upstream raw materials:

bis(bis(trimethylsilyl)amido)tin(II)

isopropyl alcohol

Downstream raw materials:

tin

Refernces