1-chloro-4-(chloromethoxy)butane

Base Information

• Chemical Name: 1-chloro-4-(chloromethoxy)butane
• CAS No.: 3970-17-0
• Molecular Formula: C5H10 Cl2 O
• Molecular Weight: 157.0383
• Mol file: 3970-17-0.mol

Synonyms:Ether,4-chlorobutyl chloromethyl (7CI,8CI); 1-Chloro-4-(chloromethoxy)butane;4-Chlorobutoxymethyl chloride; Chloromethyl 4-chlorobutyl ether; NSC 233055

Chemical Property of 1-chloro-4-(chloromethoxy)butane

Chemical Property:

• Vapor Pressure: 0.603mmHg at 25°C
• Boiling Point: 194.9°Cat760mmHg
• Flash Point: 66.9°C
• Density: 1.12g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-chloro-4-(chloromethoxy)butane

There total 7 articles about 1-chloro-4-(chloromethoxy)butane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

4-(methoxy)-1-chlorobutane (17913-18-7) → chloromethyl δ-chlorobutyl ether (3970-17-0) + methyl 1,2,2,4-tetrachlorobutyl ether (145912-06-7)

Guidance literature:

With dimethadione; sulfuryl dichloride; phenol; In dichloromethane; at 72 - 78 ℃; for 97h; Mechanism; Product distribution; other alkyl 4-chlorobutyl ethers;

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + hydrogenchloride (7647-01-0,15364-23-5) + formaldehyd (50-00-0,30525-89-4,61233-19-0) → chloromethyl δ-chlorobutyl ether (3970-17-0) + bis(4-chlorobutoxy)methane (34520-27-9)

Guidance literature:

das Paraformaldehyd reagiert;

Reference yield:

4-(methoxy)-1-chlorobutane (17913-18-7) → chloromethyl δ-chlorobutyl ether (3970-17-0) + methyl 1,4-dichlorobutyl ether (145912-13-6) + chloromethyl 1,4-dichlorobutyl ether (145912-14-7)

Guidance literature:

With chlorine; In tetrachloromethane; at 20 - 60 ℃; Title compound not separated from byproducts; Irradiation;

upstream raw materials:

tetrahydrofuran

formaldehyd

4-Chloro-1-butanol

4-(methoxy)-1-chlorobutane

Downstream raw materials:

2,3,5,6-tetramethoxybenzyl chloride

1-(4-chlorobutoxymethyl)-2,4,5-trichloroimidazole

Refernces

• 1、 Buyck, Laurent De,Pooter, Herman De. "ON THE MECHANISM OF SELECTIVE CHLORINATION OF ETHERS WITH SULFURYL CHLORIDE IN THE DARK". . p. 807 - 816. Retrieved 2007/10/02.